Synthesis and particle size control of 1,3,5-triamino-2,4,6-trinitrobenzene via vicarious nucleophilic substitution

Wen Jun Meng; Zi Hui Meng; Zhen Zhou; Ji Wei Yue; Zhi Ming Zhou; Hong Liang Wen; Yu Kai Wu

Synthesis and particle size control of 1,3,5-triamino-2,4,6-trinitrobenzene via vicarious nucleophilic substitution

Wen Jun Meng^*, Zi Hui Meng, Zhen Zhou, Ji Wei Yue, Zhi Ming Zhou, Hong Liang Wen, Yu Kai Wu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

1,3,5-triamino-2,4,6-trinitrobenzene(TATB) was synthesized with a yield of 70.6% via vicarious nucleophilic substitution (VNS) through the animation of 1,3,5-trinitrobenzene (TNB) with 4-amino-1,2,4-triazole (ATA). The product was recrystallized in Sulfuric acid. The purified product was characterized by IR, and the purity was checked by HPLC. VNS reaction was quenched by different acids, and different quencher results in different size of TATB product. The average particle sizes are 55.17, 38.83 μm and 37.29 μm, The factors which affect the size of TATB particles during recrystallization were also investigated by in-situ granule monitoring technique, and the method of preparing TATB product with different size was conveyed.

Original language	English
Pages (from-to)	29-32
Number of pages	4
Journal	Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
Volume	27
Issue number	SUPPL. 2
Publication status	Published - Dec 2007

Keywords

1,3,5-triamino-2,4,6-trinitrobenzene
Particle size control
Vicarious nucleophilic substitution

Cite this

@article{fbeb5692888f46c2afb011d457f41b66,

title = "Synthesis and particle size control of 1,3,5-triamino-2,4,6-trinitrobenzene via vicarious nucleophilic substitution",

abstract = "1,3,5-triamino-2,4,6-trinitrobenzene(TATB) was synthesized with a yield of 70.6% via vicarious nucleophilic substitution (VNS) through the animation of 1,3,5-trinitrobenzene (TNB) with 4-amino-1,2,4-triazole (ATA). The product was recrystallized in Sulfuric acid. The purified product was characterized by IR, and the purity was checked by HPLC. VNS reaction was quenched by different acids, and different quencher results in different size of TATB product. The average particle sizes are 55.17, 38.83 μm and 37.29 μm, The factors which affect the size of TATB particles during recrystallization were also investigated by in-situ granule monitoring technique, and the method of preparing TATB product with different size was conveyed.",

keywords = "1,3,5-triamino-2,4,6-trinitrobenzene, Particle size control, Vicarious nucleophilic substitution",

author = "Meng, {Wen Jun} and Meng, {Zi Hui} and Zhen Zhou and Yue, {Ji Wei} and Zhou, {Zhi Ming} and Wen, {Hong Liang} and Wu, {Yu Kai}",

year = "2007",

month = dec,

language = "English",

volume = "27",

pages = "29--32",

journal = "Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology",

issn = "1001-0645",

publisher = "Beijing Institute of Technology",

number = "SUPPL. 2",

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TY - JOUR

T1 - Synthesis and particle size control of 1,3,5-triamino-2,4,6-trinitrobenzene via vicarious nucleophilic substitution

AU - Meng, Wen Jun

AU - Meng, Zi Hui

AU - Zhou, Zhen

AU - Yue, Ji Wei

AU - Zhou, Zhi Ming

AU - Wen, Hong Liang

AU - Wu, Yu Kai

PY - 2007/12

Y1 - 2007/12

N2 - 1,3,5-triamino-2,4,6-trinitrobenzene(TATB) was synthesized with a yield of 70.6% via vicarious nucleophilic substitution (VNS) through the animation of 1,3,5-trinitrobenzene (TNB) with 4-amino-1,2,4-triazole (ATA). The product was recrystallized in Sulfuric acid. The purified product was characterized by IR, and the purity was checked by HPLC. VNS reaction was quenched by different acids, and different quencher results in different size of TATB product. The average particle sizes are 55.17, 38.83 μm and 37.29 μm, The factors which affect the size of TATB particles during recrystallization were also investigated by in-situ granule monitoring technique, and the method of preparing TATB product with different size was conveyed.

AB - 1,3,5-triamino-2,4,6-trinitrobenzene(TATB) was synthesized with a yield of 70.6% via vicarious nucleophilic substitution (VNS) through the animation of 1,3,5-trinitrobenzene (TNB) with 4-amino-1,2,4-triazole (ATA). The product was recrystallized in Sulfuric acid. The purified product was characterized by IR, and the purity was checked by HPLC. VNS reaction was quenched by different acids, and different quencher results in different size of TATB product. The average particle sizes are 55.17, 38.83 μm and 37.29 μm, The factors which affect the size of TATB particles during recrystallization were also investigated by in-situ granule monitoring technique, and the method of preparing TATB product with different size was conveyed.

KW - 1,3,5-triamino-2,4,6-trinitrobenzene

KW - Particle size control

KW - Vicarious nucleophilic substitution

UR - http://www.scopus.com/inward/record.url?scp=40749113572&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:40749113572

SN - 1001-0645

VL - 27

SP - 29

EP - 32

JO - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

JF - Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology

IS - SUPPL. 2

ER -

Synthesis and particle size control of 1,3,5-triamino-2,4,6-trinitrobenzene via vicarious nucleophilic substitution

Abstract

Keywords

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