Synthesis of 2-(dinitromethylene)-1, 3-diazacyclopentane (DNDZ) catalyzed by magnesium ion

Pan Liu; Zhi Bin Xu; Bo Zhou Wang; Zhong Xue Ge; Peng Wang; Zi Hui Meng

doi:10.3969/j.issn.1006-9941.2013.02.013

Synthesis of 2-(dinitromethylene)-1, 3-diazacyclopentane (DNDZ) catalyzed by magnesium ion

Pan Liu, Zhi Bin Xu, Bo Zhou Wang, Zhong Xue Ge, Peng Wang, Zi Hui Meng^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

As an important intermediate for new energetic materials, 2-(dinitromethylene)-1, 3-diaza- cyclopentane(DNDZ) attracts more attentions in recent years. Herein the necleophilic reaction between 1, 1-diamino-2, 2-dinitroethylene(FOX-7) and 1, 2-diaminoethane catalyzed by magnesium ion was studied and the DNDZ was synthesized in yield of 83.9% with high purity (99%) under the optimum conditions: the reaction temperature and time were 110 °C and 5.5 h respectively and the best catalyst was new prepared Mg(OAc)₂ (30%). The structure of the product was characterized by IR, NMR, MS and elemental analysis.

Original language	English
Pages (from-to)	222-225
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	21
Issue number	2
DOIs	https://doi.org/10.3969/j.issn.1006-9941.2013.02.013
Publication status	Published - Apr 2013

Keywords

1, 1-diamino-2, 2-dinitroethylene
2-(dinitromethylene)-1, 3- diazacyclopentane
Energetical material
Organic chemistry

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10.3969/j.issn.1006-9941.2013.02.013

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title = "Synthesis of 2-(dinitromethylene)-1, 3-diazacyclopentane (DNDZ) catalyzed by magnesium ion",

abstract = "As an important intermediate for new energetic materials, 2-(dinitromethylene)-1, 3-diaza- cyclopentane(DNDZ) attracts more attentions in recent years. Herein the necleophilic reaction between 1, 1-diamino-2, 2-dinitroethylene(FOX-7) and 1, 2-diaminoethane catalyzed by magnesium ion was studied and the DNDZ was synthesized in yield of 83.9% with high purity (99%) under the optimum conditions: the reaction temperature and time were 110 °C and 5.5 h respectively and the best catalyst was new prepared Mg(OAc)2 (30%). The structure of the product was characterized by IR, NMR, MS and elemental analysis.",

keywords = "1, 1-diamino-2, 2-dinitroethylene, 2-(dinitromethylene)-1, 3- diazacyclopentane, Energetical material, Organic chemistry",

author = "Pan Liu and Xu, {Zhi Bin} and Wang, {Bo Zhou} and Ge, {Zhong Xue} and Peng Wang and Meng, {Zi Hui}",

year = "2013",

month = apr,

doi = "10.3969/j.issn.1006-9941.2013.02.013",

language = "English",

volume = "21",

pages = "222--225",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "2",

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TY - JOUR

T1 - Synthesis of 2-(dinitromethylene)-1, 3-diazacyclopentane (DNDZ) catalyzed by magnesium ion

AU - Liu, Pan

AU - Xu, Zhi Bin

AU - Wang, Bo Zhou

AU - Ge, Zhong Xue

AU - Wang, Peng

AU - Meng, Zi Hui

PY - 2013/4

Y1 - 2013/4

N2 - As an important intermediate for new energetic materials, 2-(dinitromethylene)-1, 3-diaza- cyclopentane(DNDZ) attracts more attentions in recent years. Herein the necleophilic reaction between 1, 1-diamino-2, 2-dinitroethylene(FOX-7) and 1, 2-diaminoethane catalyzed by magnesium ion was studied and the DNDZ was synthesized in yield of 83.9% with high purity (99%) under the optimum conditions: the reaction temperature and time were 110 °C and 5.5 h respectively and the best catalyst was new prepared Mg(OAc)2 (30%). The structure of the product was characterized by IR, NMR, MS and elemental analysis.

AB - As an important intermediate for new energetic materials, 2-(dinitromethylene)-1, 3-diaza- cyclopentane(DNDZ) attracts more attentions in recent years. Herein the necleophilic reaction between 1, 1-diamino-2, 2-dinitroethylene(FOX-7) and 1, 2-diaminoethane catalyzed by magnesium ion was studied and the DNDZ was synthesized in yield of 83.9% with high purity (99%) under the optimum conditions: the reaction temperature and time were 110 °C and 5.5 h respectively and the best catalyst was new prepared Mg(OAc)2 (30%). The structure of the product was characterized by IR, NMR, MS and elemental analysis.

KW - 1, 1-diamino-2, 2-dinitroethylene

KW - 2-(dinitromethylene)-1, 3- diazacyclopentane

KW - Energetical material

KW - Organic chemistry

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U2 - 10.3969/j.issn.1006-9941.2013.02.013

DO - 10.3969/j.issn.1006-9941.2013.02.013

M3 - Article

AN - SCOPUS:84878761039

SN - 1006-9941

VL - 21

SP - 222

EP - 225

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 2

ER -

Synthesis of 2-(dinitromethylene)-1, 3-diazacyclopentane (DNDZ) catalyzed by magnesium ion

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Keywords

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