Abstract
Tetranitrodimerglycoluril (TNDGU) is a newly developed insensitive energetic material. Its solubility in methanol, propanone, ethyl ethanoate, and ethanenitrile between 293.15 K and 313.15 K at atmospheric pressure was investigated by the gravimetric method. The order of the solubility of TNDGU is ethanenitrile > ethyl ethanoate ≈ propanone > methanol. The solubility of TNDGU increased with an increase of temperature. The enthalpy of dissolution in each solvent was also calculated according to a modified van't Hoff equation; the values are 25.18 kJ·mol-1 for methanol, 41.26 kJ·mol-1 for propanone, 34.70 kJ·mol-1 for ethyl ethanoate, and 36.33 kJ·mol-1 for ethanenitrile, respectively.
Original language | English |
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Pages (from-to) | 2620-2622 |
Number of pages | 3 |
Journal | Journal of Chemical and Engineering Data |
Volume | 59 |
Issue number | 8 |
DOIs | |
Publication status | Published - 14 Aug 2014 |