Sodium 1,1'-dinitramino-5,5'-bistetrazolate: A 3D metal-organic framework as green energetic material with good performance and thermo stability

Piao He; Jian Guo Zhang; Le Wu; Jin Ting Wu; Tong Lai Zhang

doi:10.1016/j.ica.2016.10.031

Sodium 1,1'-dinitramino-5,5'-bistetrazolate: A 3D metal-organic framework as green energetic material with good performance and thermo stability

Piao He, Jian Guo Zhang^*, Le Wu, Jin Ting Wu, Tong Lai Zhang

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

A reticular 3D energetic metal-organic framework, sodium 1,1'-dinitramino-5,5'-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm⁻³, a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol⁻¹) combined with impressive heat of detonation (5080 kJ·kg⁻¹), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material.

Original language	English
Pages (from-to)	591-598
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	455
DOIs	https://doi.org/10.1016/j.ica.2016.10.031
Publication status	Published - 2017

Keywords

Energetic materials
Heats of detonation
Metal-organic frameworks
Nitrogen-rich heterocycles
Sensitivities

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10.1016/j.ica.2016.10.031

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title = "Sodium 1,1'-dinitramino-5,5'-bistetrazolate: A 3D metal-organic framework as green energetic material with good performance and thermo stability",

abstract = "A reticular 3D energetic metal-organic framework, sodium 1,1'-dinitramino-5,5'-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm−3, a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol−1) combined with impressive heat of detonation (5080 kJ·kg−1), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material.",

keywords = "Energetic materials, Heats of detonation, Metal-organic frameworks, Nitrogen-rich heterocycles, Sensitivities",

author = "Piao He and Zhang, {Jian Guo} and Le Wu and Wu, {Jin Ting} and Zhang, {Tong Lai}",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2017",

doi = "10.1016/j.ica.2016.10.031",

language = "English",

volume = "455",

pages = "591--598",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

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TY - JOUR

T1 - Sodium 1,1'-dinitramino-5,5'-bistetrazolate

T2 - A 3D metal-organic framework as green energetic material with good performance and thermo stability

AU - He, Piao

AU - Zhang, Jian Guo

AU - Wu, Le

AU - Wu, Jin Ting

AU - Zhang, Tong Lai

PY - 2017

Y1 - 2017

N2 - A reticular 3D energetic metal-organic framework, sodium 1,1'-dinitramino-5,5'-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm−3, a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol−1) combined with impressive heat of detonation (5080 kJ·kg−1), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material.

AB - A reticular 3D energetic metal-organic framework, sodium 1,1'-dinitramino-5,5'-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm−3, a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol−1) combined with impressive heat of detonation (5080 kJ·kg−1), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material.

KW - Energetic materials

KW - Heats of detonation

KW - Metal-organic frameworks

KW - Nitrogen-rich heterocycles

KW - Sensitivities

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U2 - 10.1016/j.ica.2016.10.031

DO - 10.1016/j.ica.2016.10.031

M3 - Article

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SN - 0020-1693

VL - 455

SP - 591

EP - 598

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Sodium 1,1'-dinitramino-5,5'-bistetrazolate: A 3D metal-organic framework as green energetic material with good performance and thermo stability

Abstract

Keywords

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