TY - JOUR
T1 - Sodium 1,1'-dinitramino-5,5'-bistetrazolate
T2 - A 3D metal-organic framework as green energetic material with good performance and thermo stability
AU - He, Piao
AU - Zhang, Jian Guo
AU - Wu, Le
AU - Wu, Jin Ting
AU - Zhang, Tong Lai
N1 - Publisher Copyright:
© 2016 Elsevier B.V.
PY - 2017
Y1 - 2017
N2 - A reticular 3D energetic metal-organic framework, sodium 1,1'-dinitramino-5,5'-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm−3, a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol−1) combined with impressive heat of detonation (5080 kJ·kg−1), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material.
AB - A reticular 3D energetic metal-organic framework, sodium 1,1'-dinitramino-5,5'-bistetrazolate was first synthesized and fully characterized by crystal X-ray diffraction, elemental analysis, mass spectrometry, IR spectroscopy, differential scanning calorimetry (DSC) and sensitivity test. It shows a density of 1.892 g·cm−3, a positive oxygen balance and a high decomposition temperature of 250 °C. The promising energetic properties were also investigated by using theoretical calculation methods. Its calculated heat of formation (529.5 kJ·mol−1) combined with impressive heat of detonation (5080 kJ·kg−1), good thermal stabilities and clean detonation products make it a competitive replacement as a green energetic material.
KW - Energetic materials
KW - Heats of detonation
KW - Metal-organic frameworks
KW - Nitrogen-rich heterocycles
KW - Sensitivities
UR - http://www.scopus.com/inward/record.url?scp=84994338651&partnerID=8YFLogxK
U2 - 10.1016/j.ica.2016.10.031
DO - 10.1016/j.ica.2016.10.031
M3 - Article
AN - SCOPUS:84994338651
SN - 0020-1693
VL - 455
SP - 591
EP - 598
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
ER -