Property study of poly nitro compounds of cis-syn-cis-2, 6-dioxodecahydro-lH, 5H-diimidazo [4, 5-b: 4′, 5′-e] pyrazine

Yang Liu, Zhibin Xu, Yudong Xu, Liang Xu, Zihui Meng

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

1 Citation (Scopus)

Abstract

Poly nitro group substituted cis-syn-cis-2, 6-dioxodecahydro-lH, 5H-diimidazo [4, 5-b: 4′, 5′-e] pyrazine derivatives are synthesized by modified method and adequately characterized. All compounds have good performance both in density (ρ> 1.85 g/cm3) and high detonation velocity (vD > 8800 m/s, calculated). Some representative compounds, for example, 4 (vD: 9405 ms-1; P: 41.6 GPa) and 5 (vD:9781 ms-1; P: 45.6 GPa) exhibit excellent detonation performances, which are comparable with current energetic compounds such as RDX (vD: 8724 ms-1; P: 35.2 GPa) and HMX (vD:9059 ms-1; P: 39.2 GPa). Considering the sensitivity increasing with the number of nitro group, two componds with tetranitro groups (2 and 3) are worthy of deep research.

Original languageEnglish
Title of host publicationAdvances in Materials, Machinery, Electronics I
Subtitle of host publicationProceedings of the International Conference on Advances in Materials, Machinery, Electronics, AMME 2017
EditorsCan Yang, Lin Liu, Jianfeng Ke
PublisherAmerican Institute of Physics Inc.
ISBN (Electronic)9780735414884
DOIs
Publication statusPublished - 13 Mar 2017
Event1st International Conference on Advances in Materials, Machinery, Electronics, AMME 2017 - Wuhan, China
Duration: 25 Feb 201726 Feb 2017

Publication series

NameAIP Conference Proceedings
Volume1820
ISSN (Print)0094-243X
ISSN (Electronic)1551-7616

Conference

Conference1st International Conference on Advances in Materials, Machinery, Electronics, AMME 2017
Country/TerritoryChina
CityWuhan
Period25/02/1726/02/17

Keywords

  • Density
  • Detonation Performance
  • Fused Aza-Polycyclic Structure
  • Poly Nitro Compounds

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