Preparation and molecular structure of [Pb2(TNR)(NO 3)2(H2O)]

Tong Lai Zhang; Yong Ming Yang; Jian Guo Zhang; Bing Shao; Li Yang; Kai Bei Yu

Preparation and molecular structure of [Pb₂(TNR)(NO ₃)₂(H₂O)]

Tong Lai Zhang^*, Yong Ming Yang, Jian Guo Zhang, Bing Shao, Li Yang, Kai Bei Yu

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

[Pb₂(TNR)(NO₃)₂(H₂O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb₂(TNR)(NO₃) ₂(H₂O) was determined by single crystal diffraction analysis. The crystal is triclinic, space group P1 with crystal parameters a = 0.7279(2) nm, b = 1.0698(2) nm, c = 1.0738(2) nm; α = 86. 82(1)°, β = 89.52(2)°, γ = 83.50(2)°; V = 0.8295(3) nm³, Z = 2, D_c = 3.201g · cm^-3, F(000) = 716. The final R value is 0.0358. In the crystal structure, one lead ion was represented by nine coordination geometry; the other was showed as ten coordination geometry.

Original language	English
Pages (from-to)	305-308
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	18
Issue number	3
Publication status	Published - 2002

Keywords

Crystal structure
Lead complex
Preparation

Cite this

Zhang, T. L., Yang, Y. M., Zhang, J. G., Shao, B., Yang, L., & Yu, K. B. (2002). Preparation and molecular structure of [Pb₂(TNR)(NO ₃)₂(H₂O)]. Chinese Journal of Inorganic Chemistry, 18(3), 305-308.

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title = "Preparation and molecular structure of [Pb2(TNR)(NO 3)2(H2O)]",

abstract = "[Pb2(TNR)(NO3)2(H2O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb2(TNR)(NO3) 2(H2O) was determined by single crystal diffraction analysis. The crystal is triclinic, space group P1 with crystal parameters a = 0.7279(2) nm, b = 1.0698(2) nm, c = 1.0738(2) nm; α = 86. 82(1)°, β = 89.52(2)°, γ = 83.50(2)°; V = 0.8295(3) nm3, Z = 2, Dc = 3.201g · cm-3, F(000) = 716. The final R value is 0.0358. In the crystal structure, one lead ion was represented by nine coordination geometry; the other was showed as ten coordination geometry.",

keywords = "Crystal structure, Lead complex, Preparation",

author = "Zhang, {Tong Lai} and Yang, {Yong Ming} and Zhang, {Jian Guo} and Bing Shao and Li Yang and Yu, {Kai Bei}",

year = "2002",

language = "English",

volume = "18",

pages = "305--308",

journal = "Chinese Journal of Inorganic Chemistry",

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publisher = "Chinese Chemical Society",

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TY - JOUR

T1 - Preparation and molecular structure of [Pb2(TNR)(NO 3)2(H2O)]

AU - Zhang, Tong Lai

AU - Yang, Yong Ming

AU - Zhang, Jian Guo

AU - Shao, Bing

AU - Yang, Li

AU - Yu, Kai Bei

PY - 2002

Y1 - 2002

N2 - [Pb2(TNR)(NO3)2(H2O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb2(TNR)(NO3) 2(H2O) was determined by single crystal diffraction analysis. The crystal is triclinic, space group P1 with crystal parameters a = 0.7279(2) nm, b = 1.0698(2) nm, c = 1.0738(2) nm; α = 86. 82(1)°, β = 89.52(2)°, γ = 83.50(2)°; V = 0.8295(3) nm3, Z = 2, Dc = 3.201g · cm-3, F(000) = 716. The final R value is 0.0358. In the crystal structure, one lead ion was represented by nine coordination geometry; the other was showed as ten coordination geometry.

AB - [Pb2(TNR)(NO3)2(H2O)] was prepared by reaction of the aqueous solution of lead nitrate and magnesium styphnate. The crystal structure of Pb2(TNR)(NO3) 2(H2O) was determined by single crystal diffraction analysis. The crystal is triclinic, space group P1 with crystal parameters a = 0.7279(2) nm, b = 1.0698(2) nm, c = 1.0738(2) nm; α = 86. 82(1)°, β = 89.52(2)°, γ = 83.50(2)°; V = 0.8295(3) nm3, Z = 2, Dc = 3.201g · cm-3, F(000) = 716. The final R value is 0.0358. In the crystal structure, one lead ion was represented by nine coordination geometry; the other was showed as ten coordination geometry.

KW - Crystal structure

KW - Lead complex

KW - Preparation

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M3 - Article

AN - SCOPUS:0345806575

SN - 1001-4861

VL - 18

SP - 305

EP - 308

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 3

ER -

Preparation and molecular structure of [Pb₂(TNR)(NO ₃)₂(H₂O)]

Abstract

Keywords

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