Post-cyclization of a bisimine-linked covalent organic framework to enhance the performance of visible-light photocatalytic hydrogen evolution

Huanyu Liu; Yueting Li; Lu Dai; Xiangjian Meng; Anwang Dong; Zimo Zhou; Huixia Lv; Pengfei Li; Bo Wang

doi:10.1039/d3py00181d

Post-cyclization of a bisimine-linked covalent organic framework to enhance the performance of visible-light photocatalytic hydrogen evolution

Huanyu Liu, Yueting Li, Lu Dai, Xiangjian Meng, Anwang Dong, Zimo Zhou, Huixia Lv, Pengfei Li^*, Bo Wang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Covalent organic frameworks (COFs) are promising candidates for the photocatalytic hydrogen evolution. Here, we reported the synthesis of a bisimine-linked COF and its partial post-cyclization to an imidazolium-linked COF. Both the chemical stability and π-electron delocalization are significantly improved by the post-cyclization, leading to a triply increased hydrogen evolution rate.

Original language	English
Pages (from-to)	1323-1329
Number of pages	7
Journal	Polymer Chemistry
Volume	14
Issue number	12
DOIs	https://doi.org/10.1039/d3py00181d
Publication status	Published - 9 Mar 2023

Access to Document

10.1039/d3py00181d

Cite this

@article{c4cd0401811f40299ea050749e1971f0,

title = "Post-cyclization of a bisimine-linked covalent organic framework to enhance the performance of visible-light photocatalytic hydrogen evolution",

abstract = "Covalent organic frameworks (COFs) are promising candidates for the photocatalytic hydrogen evolution. Here, we reported the synthesis of a bisimine-linked COF and its partial post-cyclization to an imidazolium-linked COF. Both the chemical stability and π-electron delocalization are significantly improved by the post-cyclization, leading to a triply increased hydrogen evolution rate.",

author = "Huanyu Liu and Yueting Li and Lu Dai and Xiangjian Meng and Anwang Dong and Zimo Zhou and Huixia Lv and Pengfei Li and Bo Wang",

note = "Publisher Copyright: {\textcopyright} 2023 The Royal Society of Chemistry.",

year = "2023",

month = mar,

day = "9",

doi = "10.1039/d3py00181d",

language = "English",

volume = "14",

pages = "1323--1329",

journal = "Polymer Chemistry",

issn = "1759-9954",

publisher = "Royal Society of Chemistry",

number = "12",

}

TY - JOUR

T1 - Post-cyclization of a bisimine-linked covalent organic framework to enhance the performance of visible-light photocatalytic hydrogen evolution

AU - Liu, Huanyu

AU - Li, Yueting

AU - Dai, Lu

AU - Meng, Xiangjian

AU - Dong, Anwang

AU - Zhou, Zimo

AU - Lv, Huixia

AU - Li, Pengfei

AU - Wang, Bo

PY - 2023/3/9

Y1 - 2023/3/9

N2 - Covalent organic frameworks (COFs) are promising candidates for the photocatalytic hydrogen evolution. Here, we reported the synthesis of a bisimine-linked COF and its partial post-cyclization to an imidazolium-linked COF. Both the chemical stability and π-electron delocalization are significantly improved by the post-cyclization, leading to a triply increased hydrogen evolution rate.

AB - Covalent organic frameworks (COFs) are promising candidates for the photocatalytic hydrogen evolution. Here, we reported the synthesis of a bisimine-linked COF and its partial post-cyclization to an imidazolium-linked COF. Both the chemical stability and π-electron delocalization are significantly improved by the post-cyclization, leading to a triply increased hydrogen evolution rate.

UR - http://www.scopus.com/inward/record.url?scp=85151035552&partnerID=8YFLogxK

U2 - 10.1039/d3py00181d

DO - 10.1039/d3py00181d

M3 - Article

AN - SCOPUS:85151035552

SN - 1759-9954

VL - 14

SP - 1323

EP - 1329

JO - Polymer Chemistry

JF - Polymer Chemistry

IS - 12

ER -

Post-cyclization of a bisimine-linked covalent organic framework to enhance the performance of visible-light photocatalytic hydrogen evolution

Abstract

Access to Document

Other files and links

Fingerprint

Cite this