Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid

Min Wang, Qin Wu, Han Sheng Li*, Yun Zhao, Qing Ze Jiao

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

4 Citations (Scopus)

Abstract

A polyoxometalate-based ionic liquid, 1-(4-sulfonic acid) methylimidazolium phosphotungstate ([MIMBS]3PW12O40), was synthesized and characterized by Fourier transform infrared spectrum, nuclear magnetic resonance, electrospray ionization mass spectrum and thermogravimetric analyzer. [MIMBS]3PW12O40 exhibited high activity for the extractive catalytic oxidative desulfurization process, together with H2O2 and CH3CN/H2O. The sulfur removal of DBT could reach 99.9% under wild conditions, and the catalyst could be used three times with only a slight decline in activity.

Original languageEnglish
Title of host publicationAdvances in Chemical Engineering and Advanced Materials IV
EditorsGurumurthy Hegde, Seung-Bok Choi, Huining Xiao
PublisherTrans Tech Publications Ltd.
Pages65-69
Number of pages5
ISBN (Electronic)9783038352693
DOIs
Publication statusPublished - 2014
Event4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014 - Shenzhen, China
Duration: 24 Jun 201427 Jun 2014

Publication series

NameAdvanced Materials Research
Volume1033-1034
ISSN (Print)1022-6680
ISSN (Electronic)1662-8985

Conference

Conference4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014
Country/TerritoryChina
CityShenzhen
Period24/06/1427/06/14

Keywords

  • Catalytic
  • Extraction
  • Oxidative desulfurization
  • Polyoxometalate-based ionic liquid

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