Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid

Min Wang; Qin Wu; Han Sheng Li; Yun Zhao; Qing Ze Jiao

doi:10.4028/www.scientific.net/AMR.1033-1034.65

Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid

Min Wang, Qin Wu, Han Sheng Li^*, Yun Zhao, Qing Ze Jiao

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

5 引用（Scopus）

摘要

A polyoxometalate-based ionic liquid, 1-(4-sulfonic acid) methylimidazolium phosphotungstate ([MIMBS]₃PW₁₂O₄₀), was synthesized and characterized by Fourier transform infrared spectrum, nuclear magnetic resonance, electrospray ionization mass spectrum and thermogravimetric analyzer. [MIMBS]₃PW₁₂O₄₀ exhibited high activity for the extractive catalytic oxidative desulfurization process, together with H₂O₂ and CH₃CN/H₂O. The sulfur removal of DBT could reach 99.9% under wild conditions, and the catalyst could be used three times with only a slight decline in activity.

源语言	英语
主期刊名	Advances in Chemical Engineering and Advanced Materials IV
编辑	Gurumurthy Hegde, Seung-Bok Choi, Huining Xiao
出版商	Trans Tech Publications Ltd.
页	65-69
页数	5
ISBN（电子版）	9783038352693
DOI	https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.65
出版状态	已出版 - 2014
活动	4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014 - Shenzhen, 中国期限: 24 6月 2014 → 27 6月 2014

出版系列

姓名	Advanced Materials Research
卷	1033-1034
ISSN（印刷版）	1022-6680
ISSN（电子版）	1662-8985

会议

会议	4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014
国家/地区	中国
市	Shenzhen
时期	24/06/14 → 27/06/14

访问文件

10.4028/www.scientific.net/AMR.1033-1034.65

其它文件与链接

链接到 Scopus 的出版物

引用此

Wang, M., Wu, Q., Li, H. S., Zhao, Y., & Jiao, Q. Z. (2014). Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid. 在 G. Hegde, S.-B. Choi, & H. Xiao (编辑), Advances in Chemical Engineering and Advanced Materials IV (页码 65-69). (Advanced Materials Research; 卷 1033-1034). Trans Tech Publications Ltd.. https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.65

@inproceedings{12787afb40044899b598a201698de237,

title = "Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid",

abstract = "A polyoxometalate-based ionic liquid, 1-(4-sulfonic acid) methylimidazolium phosphotungstate ([MIMBS]3PW12O40), was synthesized and characterized by Fourier transform infrared spectrum, nuclear magnetic resonance, electrospray ionization mass spectrum and thermogravimetric analyzer. [MIMBS]3PW12O40 exhibited high activity for the extractive catalytic oxidative desulfurization process, together with H2O2 and CH3CN/H2O. The sulfur removal of DBT could reach 99.9% under wild conditions, and the catalyst could be used three times with only a slight decline in activity.",

keywords = "Catalytic, Extraction, Oxidative desulfurization, Polyoxometalate-based ionic liquid",

author = "Min Wang and Qin Wu and Li, {Han Sheng} and Yun Zhao and Jiao, {Qing Ze}",

note = "Publisher Copyright: {\textcopyright} (2014) Trans Tech Publications, Switzerland.; 4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014 ; Conference date: 24-06-2014 Through 27-06-2014",

year = "2014",

doi = "10.4028/www.scientific.net/AMR.1033-1034.65",

language = "English",

series = "Advanced Materials Research",

publisher = "Trans Tech Publications Ltd.",

pages = "65--69",

editor = "Gurumurthy Hegde and Seung-Bok Choi and Huining Xiao",

booktitle = "Advances in Chemical Engineering and Advanced Materials IV",

address = "Switzerland",

}

Wang, M, Wu, Q, Li, HS, Zhao, Y & Jiao, QZ 2014, Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid. 在 G Hegde, S-B Choi & H Xiao (编辑), Advances in Chemical Engineering and Advanced Materials IV. Advanced Materials Research, 卷 1033-1034, Trans Tech Publications Ltd., 页码 65-69, 4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014, Shenzhen, 中国, 24/06/14. https://doi.org/10.4028/www.scientific.net/AMR.1033-1034.65

Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid. / Wang, Min; Wu, Qin; Li, Han Sheng 等.
Advances in Chemical Engineering and Advanced Materials IV. 编辑 / Gurumurthy Hegde; Seung-Bok Choi; Huining Xiao. Trans Tech Publications Ltd., 2014. 页码 65-69 (Advanced Materials Research; 卷 1033-1034).

科研成果: 书/报告/会议事项章节 › 会议稿件 › 同行评审

TY - GEN

T1 - Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid

AU - Wang, Min

AU - Wu, Qin

AU - Li, Han Sheng

AU - Zhao, Yun

AU - Jiao, Qing Ze

N1 - Publisher Copyright: © (2014) Trans Tech Publications, Switzerland.

PY - 2014

Y1 - 2014

N2 - A polyoxometalate-based ionic liquid, 1-(4-sulfonic acid) methylimidazolium phosphotungstate ([MIMBS]3PW12O40), was synthesized and characterized by Fourier transform infrared spectrum, nuclear magnetic resonance, electrospray ionization mass spectrum and thermogravimetric analyzer. [MIMBS]3PW12O40 exhibited high activity for the extractive catalytic oxidative desulfurization process, together with H2O2 and CH3CN/H2O. The sulfur removal of DBT could reach 99.9% under wild conditions, and the catalyst could be used three times with only a slight decline in activity.

AB - A polyoxometalate-based ionic liquid, 1-(4-sulfonic acid) methylimidazolium phosphotungstate ([MIMBS]3PW12O40), was synthesized and characterized by Fourier transform infrared spectrum, nuclear magnetic resonance, electrospray ionization mass spectrum and thermogravimetric analyzer. [MIMBS]3PW12O40 exhibited high activity for the extractive catalytic oxidative desulfurization process, together with H2O2 and CH3CN/H2O. The sulfur removal of DBT could reach 99.9% under wild conditions, and the catalyst could be used three times with only a slight decline in activity.

KW - Catalytic

KW - Extraction

KW - Oxidative desulfurization

KW - Polyoxometalate-based ionic liquid

UR - http://www.scopus.com/inward/record.url?scp=84920807462&partnerID=8YFLogxK

U2 - 10.4028/www.scientific.net/AMR.1033-1034.65

DO - 10.4028/www.scientific.net/AMR.1033-1034.65

M3 - Conference contribution

AN - SCOPUS:84920807462

T3 - Advanced Materials Research

SP - 65

EP - 69

BT - Advances in Chemical Engineering and Advanced Materials IV

A2 - Hegde, Gurumurthy

A2 - Choi, Seung-Bok

A2 - Xiao, Huining

PB - Trans Tech Publications Ltd.

T2 - 4th International Conference on Chemical Engineering and Advanced Materials, CEAM 2014

Y2 - 24 June 2014 through 27 June 2014

ER -

Oxidative desulfurization of dibenzothiophene catalyzed by polyoxometalate-based ionic liquid

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