Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH) 2 under transition metals free condition

Zhi Hao Cui; Zi Hui Meng; Yan Qing Mi; Peng Wang; Qi Wang; Lin Man Zhao; Ke Jian Cui; Fang Yu; Zhi Bin Xu

doi:10.1016/j.cclet.2011.11.009

Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH) ₂ under transition metals free condition

Zhi Hao Cui, Zi Hui Meng, Yan Qing Mi, Peng Wang, Qi Wang, Lin Man Zhao, Ke Jian Cui, Fang Yu, Zhi Bin Xu^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg(OH) ₂ without transition metals. Only using stoichiometric amount of nano sized Mg(OH) ₂, good to moderate isolated yields could be achieved in N-methylpyrrolidone (NMP) after 24 h at 150 °C.

Original language	English
Pages (from-to)	137-140
Number of pages	4
Journal	Chinese Chemical Letters
Volume	23
Issue number	2
DOIs	https://doi.org/10.1016/j.cclet.2011.11.009
Publication status	Published - Feb 2012

Keywords

Amination
Cyclic secondary amines
Electron deficient aryl chloride
Magnesium hydroxide
Nano sized

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10.1016/j.cclet.2011.11.009

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title = "Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH) 2 under transition metals free condition",

abstract = "This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg(OH) 2 without transition metals. Only using stoichiometric amount of nano sized Mg(OH) 2, good to moderate isolated yields could be achieved in N-methylpyrrolidone (NMP) after 24 h at 150 °C.",

keywords = "Amination, Cyclic secondary amines, Electron deficient aryl chloride, Magnesium hydroxide, Nano sized",

author = "Cui, {Zhi Hao} and Meng, {Zi Hui} and Mi, {Yan Qing} and Peng Wang and Qi Wang and Zhao, {Lin Man} and Cui, {Ke Jian} and Fang Yu and Xu, {Zhi Bin}",

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T1 - Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH) 2 under transition metals free condition

AU - Cui, Zhi Hao

AU - Meng, Zi Hui

AU - Mi, Yan Qing

AU - Wang, Peng

AU - Wang, Qi

AU - Zhao, Lin Man

AU - Cui, Ke Jian

AU - Yu, Fang

AU - Xu, Zhi Bin

PY - 2012/2

Y1 - 2012/2

N2 - This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg(OH) 2 without transition metals. Only using stoichiometric amount of nano sized Mg(OH) 2, good to moderate isolated yields could be achieved in N-methylpyrrolidone (NMP) after 24 h at 150 °C.

AB - This paper presents the amination reactions of electron deficient aryl chlorides promoted by Mg(OH) 2 without transition metals. Only using stoichiometric amount of nano sized Mg(OH) 2, good to moderate isolated yields could be achieved in N-methylpyrrolidone (NMP) after 24 h at 150 °C.

KW - Amination

KW - Cyclic secondary amines

KW - Electron deficient aryl chloride

KW - Magnesium hydroxide

KW - Nano sized

UR - http://www.scopus.com/inward/record.url?scp=84855926439&partnerID=8YFLogxK

U2 - 10.1016/j.cclet.2011.11.009

DO - 10.1016/j.cclet.2011.11.009

M3 - Article

AN - SCOPUS:84855926439

SN - 1001-8417

VL - 23

SP - 137

EP - 140

JO - Chinese Chemical Letters

JF - Chinese Chemical Letters

IS - 2

ER -

Amination of electron deficient aryl chlorides promoted by nano sized Mg(OH) ₂ under transition metals free condition

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Keywords

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