TY - JOUR
T1 - Activation of cyclopentadiene derivatives by an α-diimine-ligated Mg-Mg-bonded compound
AU - Qu, Yao
AU - Xi, Zhixian
AU - Sun, Zhenzhou
AU - Yang, Li
AU - Liu, Rui
AU - Dong, Ben
AU - Wu, Biao
AU - Yang, Xiao Juan
N1 - Publisher Copyright:
© 2024 The Royal Society of Chemistry.
PY - 2024/6/3
Y1 - 2024/6/3
N2 - Heteroleptic, bimetallic (Mg/K) cyclopentadienyl complexes (2-4) were synthesized by the reaction of the Mg-Mg-bonded compound [K(THF)3]2[LMg-MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with cyclopentadiene derivatives, 6,6-dimethylfulvene, 6-(dimethylamino)fulvene, or 1,2,3,4-tetramethyl-1,3-cyclopentadiene. The reactions proceed through diverse pathways, including hydrogen abstraction, C-C coupling, and dehydrogenation, depending on the property of the polyene substrate, thus providing an access to alkali/alkaline earth metal cyclopentadienyl complexes.
AB - Heteroleptic, bimetallic (Mg/K) cyclopentadienyl complexes (2-4) were synthesized by the reaction of the Mg-Mg-bonded compound [K(THF)3]2[LMg-MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with cyclopentadiene derivatives, 6,6-dimethylfulvene, 6-(dimethylamino)fulvene, or 1,2,3,4-tetramethyl-1,3-cyclopentadiene. The reactions proceed through diverse pathways, including hydrogen abstraction, C-C coupling, and dehydrogenation, depending on the property of the polyene substrate, thus providing an access to alkali/alkaline earth metal cyclopentadienyl complexes.
UR - http://www.scopus.com/inward/record.url?scp=85195801504&partnerID=8YFLogxK
U2 - 10.1039/d4dt01038h
DO - 10.1039/d4dt01038h
M3 - Article
AN - SCOPUS:85195801504
SN - 1477-9226
VL - 53
SP - 10065
EP - 10069
JO - Dalton Transactions
JF - Dalton Transactions
IS - 24
ER -