Activation of cyclopentadiene derivatives by an α-diimine-ligated Mg-Mg-bonded compound

Yao Qu; Zhixian Xi; Zhenzhou Sun; Li Yang; Rui Liu; Ben Dong; Biao Wu; Xiao Juan Yang

doi:10.1039/d4dt01038h

Activation of cyclopentadiene derivatives by an α-diimine-ligated Mg-Mg-bonded compound

Yao Qu, Zhixian Xi, Zhenzhou Sun, Li Yang, Rui Liu, Ben Dong, Biao Wu, Xiao Juan Yang^*

^*此作品的通讯作者

化学与化工学院

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Heteroleptic, bimetallic (Mg/K) cyclopentadienyl complexes (2-4) were synthesized by the reaction of the Mg-Mg-bonded compound [K(THF)₃]₂[LMg-MgL] (1, L = [(2,6-iPr₂C₆H₃)NC(CH₃)]₂²⁻) with cyclopentadiene derivatives, 6,6-dimethylfulvene, 6-(dimethylamino)fulvene, or 1,2,3,4-tetramethyl-1,3-cyclopentadiene. The reactions proceed through diverse pathways, including hydrogen abstraction, C-C coupling, and dehydrogenation, depending on the property of the polyene substrate, thus providing an access to alkali/alkaline earth metal cyclopentadienyl complexes.

源语言	英语
页（从-至）	10065-10069
页数	5
期刊	Dalton Transactions
卷	53
期	24
DOI	https://doi.org/10.1039/d4dt01038h
出版状态	已出版 - 3 6月 2024

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10.1039/d4dt01038h

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Qu, Y., Xi, Z., Sun, Z., Yang, L., Liu, R., Dong, B., Wu, B., & Yang, X. J. (2024). Activation of cyclopentadiene derivatives by an α-diimine-ligated Mg-Mg-bonded compound. Dalton Transactions, 53(24), 10065-10069. https://doi.org/10.1039/d4dt01038h

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title = "Activation of cyclopentadiene derivatives by an α-diimine-ligated Mg-Mg-bonded compound",

abstract = "Heteroleptic, bimetallic (Mg/K) cyclopentadienyl complexes (2-4) were synthesized by the reaction of the Mg-Mg-bonded compound [K(THF)3]2[LMg-MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with cyclopentadiene derivatives, 6,6-dimethylfulvene, 6-(dimethylamino)fulvene, or 1,2,3,4-tetramethyl-1,3-cyclopentadiene. The reactions proceed through diverse pathways, including hydrogen abstraction, C-C coupling, and dehydrogenation, depending on the property of the polyene substrate, thus providing an access to alkali/alkaline earth metal cyclopentadienyl complexes.",

author = "Yao Qu and Zhixian Xi and Zhenzhou Sun and Li Yang and Rui Liu and Ben Dong and Biao Wu and Yang, {Xiao Juan}",

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year = "2024",

month = jun,

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doi = "10.1039/d4dt01038h",

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AU - Qu, Yao

AU - Xi, Zhixian

AU - Sun, Zhenzhou

AU - Yang, Li

AU - Liu, Rui

AU - Dong, Ben

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2024/6/3

Y1 - 2024/6/3

N2 - Heteroleptic, bimetallic (Mg/K) cyclopentadienyl complexes (2-4) were synthesized by the reaction of the Mg-Mg-bonded compound [K(THF)3]2[LMg-MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with cyclopentadiene derivatives, 6,6-dimethylfulvene, 6-(dimethylamino)fulvene, or 1,2,3,4-tetramethyl-1,3-cyclopentadiene. The reactions proceed through diverse pathways, including hydrogen abstraction, C-C coupling, and dehydrogenation, depending on the property of the polyene substrate, thus providing an access to alkali/alkaline earth metal cyclopentadienyl complexes.

AB - Heteroleptic, bimetallic (Mg/K) cyclopentadienyl complexes (2-4) were synthesized by the reaction of the Mg-Mg-bonded compound [K(THF)3]2[LMg-MgL] (1, L = [(2,6-iPr2C6H3)NC(CH3)]22−) with cyclopentadiene derivatives, 6,6-dimethylfulvene, 6-(dimethylamino)fulvene, or 1,2,3,4-tetramethyl-1,3-cyclopentadiene. The reactions proceed through diverse pathways, including hydrogen abstraction, C-C coupling, and dehydrogenation, depending on the property of the polyene substrate, thus providing an access to alkali/alkaline earth metal cyclopentadienyl complexes.

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

Activation of cyclopentadiene derivatives by an α-diimine-ligated Mg-Mg-bonded compound

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