Two New Borates Built by Different Types of {B9} Cluster Units

Juan Chen; Jiajia Wang; Chongan Chen; Guoyu Yang

doi:10.1007/s40242-022-1473-7

Two New Borates Built by Different Types of {B₉} Cluster Units

Juan Chen, Jiajia Wang, Chongan Chen, Guoyu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

Two new belt-like borates Na₄[B₉O₁₄(OH)₃]·0.5H₂O(1) and Na₅[B₉O₁₄(OH)₄](2) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B₉O₁₆(OH)_n⁽ⁿ⁺⁵⁾⁻[n=3(1), 4(2)] clusters, which are constructed from four B₃O₃ rings via three BO₄ tetrahedra. Compound 1 exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B₉O₁₆(OH)₃⁸⁻ clusters. Compound 2 features two different 1D belts built by different B₉O₁₆(OH)₄⁹⁻ units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds 1 and 2 have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.

Original language	English
Pages (from-to)	744-749
Number of pages	6
Journal	Chemical Research in Chinese Universities
Volume	38
Issue number	3
DOIs	https://doi.org/10.1007/s40242-022-1473-7
Publication status	Published - Jun 2022

Keywords

Borate
Oxoboron cluster
Structure
Supramolecular framework
Synthesis

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@article{0eeb56e092d94e87b7839be6bdc6e6c2,

title = "Two New Borates Built by Different Types of {B9} Cluster Units",

abstract = "Two new belt-like borates Na4[B9O14(OH)3]·0.5H2O(1) and Na5[B9O14(OH)4](2) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B9O16(OH)n(n+5)−[n=3(1), 4(2)] clusters, which are constructed from four B3O3 rings via three BO4 tetrahedra. Compound 1 exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B9O16(OH)38− clusters. Compound 2 features two different 1D belts built by different B9O16(OH)49− units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds 1 and 2 have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.",

keywords = "Borate, Oxoboron cluster, Structure, Supramolecular framework, Synthesis",

author = "Juan Chen and Jiajia Wang and Chongan Chen and Guoyu Yang",

note = "Publisher Copyright: {\textcopyright} 2022, Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH.",

year = "2022",

month = jun,

doi = "10.1007/s40242-022-1473-7",

language = "English",

volume = "38",

pages = "744--749",

journal = "Chemical Research in Chinese Universities",

issn = "1005-9040",

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TY - JOUR

T1 - Two New Borates Built by Different Types of {B9} Cluster Units

AU - Chen, Juan

AU - Wang, Jiajia

AU - Chen, Chongan

AU - Yang, Guoyu

PY - 2022/6

Y1 - 2022/6

N2 - Two new belt-like borates Na4[B9O14(OH)3]·0.5H2O(1) and Na5[B9O14(OH)4](2) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B9O16(OH)n(n+5)−[n=3(1), 4(2)] clusters, which are constructed from four B3O3 rings via three BO4 tetrahedra. Compound 1 exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B9O16(OH)38− clusters. Compound 2 features two different 1D belts built by different B9O16(OH)49− units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds 1 and 2 have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.

AB - Two new belt-like borates Na4[B9O14(OH)3]·0.5H2O(1) and Na5[B9O14(OH)4](2) have been synthesized under solvothermal conditions. Both compounds contain unprecedented B9O16(OH)n(n+5)−[n=3(1), 4(2)] clusters, which are constructed from four B3O3 rings via three BO4 tetrahedra. Compound 1 exhibits a rare 1D belt with two types of 8-membered ring(MR) windows based on B9O16(OH)38− clusters. Compound 2 features two different 1D belts built by different B9O16(OH)49− units, which is first discovered in borate family. UV-Vis diffuse reflectance spectra reveal that compounds 1 and 2 have the cut-off edges below 190 nm, indicating that they may have potential application in deep UV(DUV) region.

KW - Borate

KW - Oxoboron cluster

KW - Structure

KW - Supramolecular framework

KW - Synthesis

UR - http://www.scopus.com/inward/record.url?scp=85126049838&partnerID=8YFLogxK

U2 - 10.1007/s40242-022-1473-7

DO - 10.1007/s40242-022-1473-7

M3 - Article

AN - SCOPUS:85126049838

SN - 1005-9040

VL - 38

SP - 744

EP - 749

JO - Chemical Research in Chinese Universities

JF - Chemical Research in Chinese Universities

IS - 3

ER -

Two New Borates Built by Different Types of {B₉} Cluster Units

Abstract

Keywords

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