Two layered galloborates from centric to acentric structures: syntheses and NLO properties

Chong An Chen; Wen Fang Liu; Guo Yu Yang

doi:10.1039/d2cc03117e

Two layered galloborates from centric to acentric structures: syntheses and NLO properties

Chong An Chen, Wen Fang Liu, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Two layered galloborates (GBOs), Na₃GaB₄O₉ (1) and Na₅Ga[B₇O₁₂(OH)]₂·2B(OH)₃ (2), have been solvothermally made. 1 exhibits an unprecedented layer built by GaO₄ tetrahedra and B₄O₉ clusters. 2 was made by raising the ratio of B/Ga and the reaction temperature of 1, featuring a 2D acentric layer built by GaO₄ groups and B₇O₁₃(OH) clusters. 2 shows the highest second-harmonic generation (SHG) response of 4.6 times that of KDP (KH₂PO₄) among main group metal borates (MBOs).

Original language	English
Pages (from-to)	8718-8721
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	62
DOIs	https://doi.org/10.1039/d2cc03117e
Publication status	Published - 8 Jul 2022

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title = "Two layered galloborates from centric to acentric structures: syntheses and NLO properties",

abstract = "Two layered galloborates (GBOs), Na3GaB4O9 (1) and Na5Ga[B7O12(OH)]2·2B(OH)3 (2), have been solvothermally made. 1 exhibits an unprecedented layer built by GaO4 tetrahedra and B4O9 clusters. 2 was made by raising the ratio of B/Ga and the reaction temperature of 1, featuring a 2D acentric layer built by GaO4 groups and B7O13(OH) clusters. 2 shows the highest second-harmonic generation (SHG) response of 4.6 times that of KDP (KH2PO4) among main group metal borates (MBOs).",

author = "Chen, {Chong An} and Liu, {Wen Fang} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

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journal = "Chemical Communications",

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T2 - syntheses and NLO properties

AU - Chen, Chong An

AU - Liu, Wen Fang

AU - Yang, Guo Yu

PY - 2022/7/8

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N2 - Two layered galloborates (GBOs), Na3GaB4O9 (1) and Na5Ga[B7O12(OH)]2·2B(OH)3 (2), have been solvothermally made. 1 exhibits an unprecedented layer built by GaO4 tetrahedra and B4O9 clusters. 2 was made by raising the ratio of B/Ga and the reaction temperature of 1, featuring a 2D acentric layer built by GaO4 groups and B7O13(OH) clusters. 2 shows the highest second-harmonic generation (SHG) response of 4.6 times that of KDP (KH2PO4) among main group metal borates (MBOs).

AB - Two layered galloborates (GBOs), Na3GaB4O9 (1) and Na5Ga[B7O12(OH)]2·2B(OH)3 (2), have been solvothermally made. 1 exhibits an unprecedented layer built by GaO4 tetrahedra and B4O9 clusters. 2 was made by raising the ratio of B/Ga and the reaction temperature of 1, featuring a 2D acentric layer built by GaO4 groups and B7O13(OH) clusters. 2 shows the highest second-harmonic generation (SHG) response of 4.6 times that of KDP (KH2PO4) among main group metal borates (MBOs).

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EP - 8721

JO - Chemical Communications

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Two layered galloborates from centric to acentric structures: syntheses and NLO properties

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