Two environmentally friendly energetic salts (en)(PA)2·2H2O and (pn)(PA)2·H2O based on ethylenediamine (en), 1, 3-diaminopropane (pn) and picrate (PA)

Yi Tong; Bi Dong Wu; Wen Jie Wang; Yan Gang Bi; Tong Lai Zhang; Li Yang; Jian Guo Zhang; Zun Ning Zhou

Two environmentally friendly energetic salts (en)(PA)₂·2H₂O and (pn)(PA)₂·H₂O based on ethylenediamine (en), 1, 3-diaminopropane (pn) and picrate (PA)

Yi Tong^*, Bi Dong Wu, Wen Jie Wang, Yan Gang Bi, Tong Lai Zhang, Li Yang, Jian Guo Zhang, Zun Ning Zhou

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Two environmentally friendly energetic salts (en)(PA)₂·2H₂O (1) and (pn)(PA)₂·H₂O (2) (en=ethylenediamine, pn=1, 3-diaminopropane and PA=picrate) were synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal structures were determined by X-ray single crystal diffraction. The results show that they belong to the orthorhombic space group Pnma. Thermal decomposition mechanisms were investigated through differential scanning calorimetry (DSC) and thermo-gravimetric analysis (TGA). The non-isothermal kinetics parameters were also studied by applying the Kissinger and Ozawa's methods. In addition, the experimental data showed that the energies of combustion of 1 and 2 were slightly higher than to the energies of combustion of RDX (1, 3, 5-trinitro-1, 3, 5-triaza-cyclohexane) and HMX (1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazocane). Determination of the sensitivities revealed lower sensitivities as compared to KPA (potassium picrate).

Original language	English
Pages (from-to)	98-105
Number of pages	8
Journal	Journal of Beijing Institute of Technology (English Edition)
Volume	23
Issue number	SUPPL.1
Publication status	Published - 2014

Keywords

1, 3-diaminopropane
Crystal
Decomposition
Ethylenediamine
Picrate

Cite this

@article{d4df82745f26498b8a9d9e8c4e839c23,

title = "Two environmentally friendly energetic salts (en)(PA)2·2H2O and (pn)(PA)2·H2O based on ethylenediamine (en), 1, 3-diaminopropane (pn) and picrate (PA)",

abstract = "Two environmentally friendly energetic salts (en)(PA)2·2H2O (1) and (pn)(PA)2·H2O (2) (en=ethylenediamine, pn=1, 3-diaminopropane and PA=picrate) were synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal structures were determined by X-ray single crystal diffraction. The results show that they belong to the orthorhombic space group Pnma. Thermal decomposition mechanisms were investigated through differential scanning calorimetry (DSC) and thermo-gravimetric analysis (TGA). The non-isothermal kinetics parameters were also studied by applying the Kissinger and Ozawa's methods. In addition, the experimental data showed that the energies of combustion of 1 and 2 were slightly higher than to the energies of combustion of RDX (1, 3, 5-trinitro-1, 3, 5-triaza-cyclohexane) and HMX (1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazocane). Determination of the sensitivities revealed lower sensitivities as compared to KPA (potassium picrate).",

keywords = "1, 3-diaminopropane, Crystal, Decomposition, Ethylenediamine, Picrate",

author = "Yi Tong and Wu, {Bi Dong} and Wang, {Wen Jie} and Bi, {Yan Gang} and Zhang, {Tong Lai} and Li Yang and Zhang, {Jian Guo} and Zhou, {Zun Ning}",

year = "2014",

language = "English",

volume = "23",

pages = "98--105",

journal = "Journal of Beijing Institute of Technology (English Edition)",

issn = "1004-0579",

publisher = "Beijing Institute of Technology",

number = "SUPPL.1",

}

Two environmentally friendly energetic salts (en)(PA)₂·2H₂O and (pn)(PA)₂·H₂O based on ethylenediamine (en), 1, 3-diaminopropane (pn) and picrate (PA). / Tong, Yi; Wu, Bi Dong; Wang, Wen Jie et al.
In: Journal of Beijing Institute of Technology (English Edition), Vol. 23, No. SUPPL.1, 2014, p. 98-105.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Two environmentally friendly energetic salts (en)(PA)2·2H2O and (pn)(PA)2·H2O based on ethylenediamine (en), 1, 3-diaminopropane (pn) and picrate (PA)

AU - Tong, Yi

AU - Wu, Bi Dong

AU - Wang, Wen Jie

AU - Bi, Yan Gang

AU - Zhang, Tong Lai

AU - Yang, Li

AU - Zhang, Jian Guo

AU - Zhou, Zun Ning

PY - 2014

Y1 - 2014

N2 - Two environmentally friendly energetic salts (en)(PA)2·2H2O (1) and (pn)(PA)2·H2O (2) (en=ethylenediamine, pn=1, 3-diaminopropane and PA=picrate) were synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal structures were determined by X-ray single crystal diffraction. The results show that they belong to the orthorhombic space group Pnma. Thermal decomposition mechanisms were investigated through differential scanning calorimetry (DSC) and thermo-gravimetric analysis (TGA). The non-isothermal kinetics parameters were also studied by applying the Kissinger and Ozawa's methods. In addition, the experimental data showed that the energies of combustion of 1 and 2 were slightly higher than to the energies of combustion of RDX (1, 3, 5-trinitro-1, 3, 5-triaza-cyclohexane) and HMX (1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazocane). Determination of the sensitivities revealed lower sensitivities as compared to KPA (potassium picrate).

AB - Two environmentally friendly energetic salts (en)(PA)2·2H2O (1) and (pn)(PA)2·H2O (2) (en=ethylenediamine, pn=1, 3-diaminopropane and PA=picrate) were synthesized and characterized by elemental analysis and FT-IR spectroscopy. The crystal structures were determined by X-ray single crystal diffraction. The results show that they belong to the orthorhombic space group Pnma. Thermal decomposition mechanisms were investigated through differential scanning calorimetry (DSC) and thermo-gravimetric analysis (TGA). The non-isothermal kinetics parameters were also studied by applying the Kissinger and Ozawa's methods. In addition, the experimental data showed that the energies of combustion of 1 and 2 were slightly higher than to the energies of combustion of RDX (1, 3, 5-trinitro-1, 3, 5-triaza-cyclohexane) and HMX (1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetraazocane). Determination of the sensitivities revealed lower sensitivities as compared to KPA (potassium picrate).

KW - 1, 3-diaminopropane

KW - Crystal

KW - Decomposition

KW - Ethylenediamine

KW - Picrate

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M3 - Article

AN - SCOPUS:84900474904

SN - 1004-0579

VL - 23

SP - 98

EP - 105

JO - Journal of Beijing Institute of Technology (English Edition)

JF - Journal of Beijing Institute of Technology (English Edition)

IS - SUPPL.1

ER -

Two environmentally friendly energetic salts (en)(PA)₂·2H₂O and (pn)(PA)₂·H₂O based on ethylenediamine (en), 1, 3-diaminopropane (pn) and picrate (PA)

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Keywords

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