TY - JOUR
T1 - The structure of cis-[chloro(dimethylsulfoxide)bis(1,10-phenanthroline) ruthenium(II)]-tetraphenylborate, [RuCl(DMSO)(1,10-phen)2][BPh 4]
AU - Wu, Biao
AU - Janiak, Christoph
PY - 2005
Y1 - 2005
N2 - The complex cis-[RuCl(DMSO)(phen)2]BPh4, where DMSO is dimethylsulfoxide and phen is 1,10-phenanthroline, crystallizes in the monoclinic space group P21/c with a = 19.505(4), b = 10.045(2), c = 21.199(4) Å, β = 90.137(4)°, V = 4153(2) Å3, Z = 4, Dcalc = 1.430 g cm-3. The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis-RuN 4ClS arrangement of the ligand donor atoms. The Ru-Cl distance is 2.421(1) Å and the Ru-S distance 2.250(2) Å. The four Ru-N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) Å with the Ru-N bond trans to Cl the second shortest and the Ru-N bond trans to S the longest one.
AB - The complex cis-[RuCl(DMSO)(phen)2]BPh4, where DMSO is dimethylsulfoxide and phen is 1,10-phenanthroline, crystallizes in the monoclinic space group P21/c with a = 19.505(4), b = 10.045(2), c = 21.199(4) Å, β = 90.137(4)°, V = 4153(2) Å3, Z = 4, Dcalc = 1.430 g cm-3. The ruthenium coordination geometry is that of a slightly distorted octahedron with a cis-RuN 4ClS arrangement of the ligand donor atoms. The Ru-Cl distance is 2.421(1) Å and the Ru-S distance 2.250(2) Å. The four Ru-N distances are 2.057(6), 2.066(4), 2.073(4), and 2.086(4) Å with the Ru-N bond trans to Cl the second shortest and the Ru-N bond trans to S the longest one.
KW - 1,10-Phenanthroline
KW - Crystal Structure
KW - Dimethylsulfoxide (DMSO)
KW - Ruthenium(II)
UR - http://www.scopus.com/inward/record.url?scp=12344278051&partnerID=8YFLogxK
U2 - 10.1002/zaac.200400387
DO - 10.1002/zaac.200400387
M3 - Article
AN - SCOPUS:12344278051
SN - 0044-2313
VL - 631
SP - 17
EP - 18
JO - Zeitschrift fur Anorganische und Allgemeine Chemie
JF - Zeitschrift fur Anorganische und Allgemeine Chemie
IS - 1
ER -