The first 2-D organic-inorganic hybrid containing two types of hexa-Cu II sandwiched polyoxotungstate units and mixed amines

Rui Qin Li; Yan Ying Li; Bai Feng Yang; Huan He; Jun Wei Zhao; Guo Yu Yang

doi:10.1016/j.inoche.2014.03.033

The first 2-D organic-inorganic hybrid containing two types of hexa-Cu ^II sandwiched polyoxotungstate units and mixed amines

Rui Qin Li, Yan Ying Li, Bai Feng Yang, Huan He, Jun Wei Zhao^*, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A novel 2-D hexa-Cu^II substituted sandwich-type polyoxotungstate [Cu(H₂O)₄][Cu(dien)(H₂O)₂] ₂[Cu(dien)(H₂O)]₂[Cu₆(en) ₂(H₂O)₂(B-α-HGeW₉O ₃₄)₂][Cu₆(Hdien)₂(H ₂O)₂(B-α-HGeW₉O₃₄) ₂]·24 H₂O (1, en = ethylenediamine, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. 1 represents the first 2-D inorganic-organic hybrid sandwich-type germanotungstate constructed by two kinds of hexa-Cu^II substituted sandwich-type POM hybrid units accompanying the mixed organoamine components in the structure. The TGA curve of 1 displays two continuous weight loss stages.

Original language	English
Pages (from-to)	191-194
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	44
DOIs	https://doi.org/10.1016/j.inoche.2014.03.033
Publication status	Published - Jun 2014

Keywords

Hydrothermal synthesis
Mixed amines
Polyoxometalate
Sandwich-type structure

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10.1016/j.inoche.2014.03.033

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title = "The first 2-D organic-inorganic hybrid containing two types of hexa-Cu II sandwiched polyoxotungstate units and mixed amines",

abstract = "A novel 2-D hexa-CuII substituted sandwich-type polyoxotungstate [Cu(H2O)4][Cu(dien)(H2O)2] 2[Cu(dien)(H2O)]2[Cu6(en) 2(H2O)2(B-α-HGeW9O 34)2][Cu6(Hdien)2(H 2O)2(B-α-HGeW9O34) 2]·24 H2O (1, en = ethylenediamine, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. 1 represents the first 2-D inorganic-organic hybrid sandwich-type germanotungstate constructed by two kinds of hexa-CuII substituted sandwich-type POM hybrid units accompanying the mixed organoamine components in the structure. The TGA curve of 1 displays two continuous weight loss stages.",

keywords = "Hydrothermal synthesis, Mixed amines, Polyoxometalate, Sandwich-type structure",

author = "Li, {Rui Qin} and Li, {Yan Ying} and Yang, {Bai Feng} and Huan He and Zhao, {Jun Wei} and Yang, {Guo Yu}",

year = "2014",

month = jun,

doi = "10.1016/j.inoche.2014.03.033",

language = "English",

volume = "44",

pages = "191--194",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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T1 - The first 2-D organic-inorganic hybrid containing two types of hexa-Cu II sandwiched polyoxotungstate units and mixed amines

AU - Li, Rui Qin

AU - Li, Yan Ying

AU - Yang, Bai Feng

AU - He, Huan

AU - Zhao, Jun Wei

AU - Yang, Guo Yu

PY - 2014/6

Y1 - 2014/6

N2 - A novel 2-D hexa-CuII substituted sandwich-type polyoxotungstate [Cu(H2O)4][Cu(dien)(H2O)2] 2[Cu(dien)(H2O)]2[Cu6(en) 2(H2O)2(B-α-HGeW9O 34)2][Cu6(Hdien)2(H 2O)2(B-α-HGeW9O34) 2]·24 H2O (1, en = ethylenediamine, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. 1 represents the first 2-D inorganic-organic hybrid sandwich-type germanotungstate constructed by two kinds of hexa-CuII substituted sandwich-type POM hybrid units accompanying the mixed organoamine components in the structure. The TGA curve of 1 displays two continuous weight loss stages.

AB - A novel 2-D hexa-CuII substituted sandwich-type polyoxotungstate [Cu(H2O)4][Cu(dien)(H2O)2] 2[Cu(dien)(H2O)]2[Cu6(en) 2(H2O)2(B-α-HGeW9O 34)2][Cu6(Hdien)2(H 2O)2(B-α-HGeW9O34) 2]·24 H2O (1, en = ethylenediamine, dien = diethylenetriamine) has been hydrothermally synthesized and structurally characterized by elemental analyses, IR spectroscopy, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. 1 represents the first 2-D inorganic-organic hybrid sandwich-type germanotungstate constructed by two kinds of hexa-CuII substituted sandwich-type POM hybrid units accompanying the mixed organoamine components in the structure. The TGA curve of 1 displays two continuous weight loss stages.

KW - Hydrothermal synthesis

KW - Mixed amines

KW - Polyoxometalate

KW - Sandwich-type structure

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U2 - 10.1016/j.inoche.2014.03.033

DO - 10.1016/j.inoche.2014.03.033

M3 - Article

AN - SCOPUS:84898655166

SN - 1387-7003

VL - 44

SP - 191

EP - 194

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

The first 2-D organic-inorganic hybrid containing two types of hexa-Cu ^II sandwiched polyoxotungstate units and mixed amines

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Keywords

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