Synthesis, characterization, and the molecular structures of two new kinds of stilbene

Yan Hong Liu; Tong Lai Zhang; Jian Guo Zhang; Li Yang; Jin Yu Guo; Wei Yu; Rui Feng Wu; Kai Bei Yu

doi:10.1139/V06-083

Synthesis, characterization, and the molecular structures of two new kinds of stilbene

Yan Hong Liu, Tong Lai Zhang^*, Jian Guo Zhang, Li Yang, Jin Yu Guo, Wei Yu, Rui Feng Wu, Kai Bei Yu

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

We report in this study the synthesis, crystal culture, and single-crystal X-ray crystallography of two new kinds of double stilbene, which were readily prepared from trinitro-p-xylene and p-tolualdehyde in the presence of piperidine. We found that these triclinic crystals belong to the space group P-1. These compounds were also investigated using FT-IR, ¹H NMR, ¹³C NMR, and MS spectroscopy techniques. The thermal decomposition processes of the compounds were tested by DSC and TG-DTG at a heating rate of 10 °C/min. These results indicate that the compounds have high heat-resistant stability.

Original language	English
Pages (from-to)	867-873
Number of pages	7
Journal	Canadian Journal of Chemistry
Volume	84
Issue number	6
DOIs	https://doi.org/10.1139/V06-083
Publication status	Published - Jun 2006

Keywords

Molecular structure
Polynitrostilbene
Thermal decomposition

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10.1139/V06-083

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title = "Synthesis, characterization, and the molecular structures of two new kinds of stilbene",

abstract = "We report in this study the synthesis, crystal culture, and single-crystal X-ray crystallography of two new kinds of double stilbene, which were readily prepared from trinitro-p-xylene and p-tolualdehyde in the presence of piperidine. We found that these triclinic crystals belong to the space group P-1. These compounds were also investigated using FT-IR, 1H NMR, 13C NMR, and MS spectroscopy techniques. The thermal decomposition processes of the compounds were tested by DSC and TG-DTG at a heating rate of 10 °C/min. These results indicate that the compounds have high heat-resistant stability.",

keywords = "Molecular structure, Polynitrostilbene, Thermal decomposition",

author = "Liu, {Yan Hong} and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Li Yang and Guo, {Jin Yu} and Wei Yu and Wu, {Rui Feng} and Yu, {Kai Bei}",

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T1 - Synthesis, characterization, and the molecular structures of two new kinds of stilbene

AU - Liu, Yan Hong

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Yang, Li

AU - Guo, Jin Yu

AU - Yu, Wei

AU - Wu, Rui Feng

AU - Yu, Kai Bei

PY - 2006/6

Y1 - 2006/6

N2 - We report in this study the synthesis, crystal culture, and single-crystal X-ray crystallography of two new kinds of double stilbene, which were readily prepared from trinitro-p-xylene and p-tolualdehyde in the presence of piperidine. We found that these triclinic crystals belong to the space group P-1. These compounds were also investigated using FT-IR, 1H NMR, 13C NMR, and MS spectroscopy techniques. The thermal decomposition processes of the compounds were tested by DSC and TG-DTG at a heating rate of 10 °C/min. These results indicate that the compounds have high heat-resistant stability.

AB - We report in this study the synthesis, crystal culture, and single-crystal X-ray crystallography of two new kinds of double stilbene, which were readily prepared from trinitro-p-xylene and p-tolualdehyde in the presence of piperidine. We found that these triclinic crystals belong to the space group P-1. These compounds were also investigated using FT-IR, 1H NMR, 13C NMR, and MS spectroscopy techniques. The thermal decomposition processes of the compounds were tested by DSC and TG-DTG at a heating rate of 10 °C/min. These results indicate that the compounds have high heat-resistant stability.

KW - Molecular structure

KW - Polynitrostilbene

KW - Thermal decomposition

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U2 - 10.1139/V06-083

DO - 10.1139/V06-083

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AN - SCOPUS:33748618454

SN - 0008-4042

VL - 84

SP - 867

EP - 873

JO - Canadian Journal of Chemistry

JF - Canadian Journal of Chemistry

IS - 6

ER -

Synthesis, characterization, and the molecular structures of two new kinds of stilbene

Abstract

Keywords

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