Synthesis and structure of a zinc-zinc-bonded compound with a monoanionic a-diimine ligand, [LZn-ZnL] (L = [(2,6-iPr2C 6H3)NC(Me)]2-)

Yanyan Liu; Shaoguang Li; Xiao Juan Yang; Peiju Yang; Jing Gao; Yana Xia; Biao Wu

doi:10.1021/om900408a

Synthesis and structure of a zinc-zinc-bonded compound with a monoanionic a-diimine ligand, [LZn-ZnL] (L = [(2,6-ⁱPr₂C ₆H₃)NC(Me)]₂^-)

Yanyan Liu, Shaoguang Li, Xiao Juan Yang, Peiju Yang, Jing Gao, Yana Xia, Biao Wu^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

A zinc-zinc-bonded compound with a monoanionic α-diimine ligand, [LZn-ZnL] (L = [(2,6-ⁱPr₂C₆H ₃)NC(Me)]^-₂) (3), has been synthesized by the reaction of ZnCl₂ and [Na₂L]. The Zn-Zn bond distance (2.3403(18) Å) is shorter than that in the analogues with the dianionic ligand.

Original language	English
Pages (from-to)	5270-5272
Number of pages	3
Journal	Organometallics
Volume	28
Issue number	17
DOIs	https://doi.org/10.1021/om900408a
Publication status	Published - 14 Sept 2009
Externally published	Yes

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title = "Synthesis and structure of a zinc-zinc-bonded compound with a monoanionic a-diimine ligand, [LZn-ZnL] (L = [(2,6-iPr2C 6H3)NC(Me)]2-)",

abstract = "A zinc-zinc-bonded compound with a monoanionic α-diimine ligand, [LZn-ZnL] (L = [(2,6-iPr2C6H 3)NC(Me)]-2) (3), has been synthesized by the reaction of ZnCl2 and [Na2L]. The Zn-Zn bond distance (2.3403(18) {\AA}) is shorter than that in the analogues with the dianionic ligand.",

author = "Yanyan Liu and Shaoguang Li and Yang, {Xiao Juan} and Peiju Yang and Jing Gao and Yana Xia and Biao Wu",

year = "2009",

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doi = "10.1021/om900408a",

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T1 - Synthesis and structure of a zinc-zinc-bonded compound with a monoanionic a-diimine ligand, [LZn-ZnL] (L = [(2,6-iPr2C 6H3)NC(Me)]2-)

AU - Liu, Yanyan

AU - Li, Shaoguang

AU - Yang, Xiao Juan

AU - Yang, Peiju

AU - Gao, Jing

AU - Xia, Yana

AU - Wu, Biao

PY - 2009/9/14

Y1 - 2009/9/14

N2 - A zinc-zinc-bonded compound with a monoanionic α-diimine ligand, [LZn-ZnL] (L = [(2,6-iPr2C6H 3)NC(Me)]-2) (3), has been synthesized by the reaction of ZnCl2 and [Na2L]. The Zn-Zn bond distance (2.3403(18) Å) is shorter than that in the analogues with the dianionic ligand.

AB - A zinc-zinc-bonded compound with a monoanionic α-diimine ligand, [LZn-ZnL] (L = [(2,6-iPr2C6H 3)NC(Me)]-2) (3), has been synthesized by the reaction of ZnCl2 and [Na2L]. The Zn-Zn bond distance (2.3403(18) Å) is shorter than that in the analogues with the dianionic ligand.

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U2 - 10.1021/om900408a

DO - 10.1021/om900408a

M3 - Article

AN - SCOPUS:69949139757

SN - 0276-7333

VL - 28

SP - 5270

EP - 5272

JO - Organometallics

JF - Organometallics

IS - 17

ER -

Synthesis and structure of a zinc-zinc-bonded compound with a monoanionic a-diimine ligand, [LZn-ZnL] (L = [(2,6-ⁱPr₂C ₆H₃)NC(Me)]₂^-)

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