Synthesis and crystal structure of 7-nitro-5-sulfo-napthalene-1,4- dicarboxylate acid

Rui Feng Wu; Tong Lai Zhang; Xiao Jing Qiao; Jian Guo Zhang; Li Yang; Wei Yu

Synthesis and crystal structure of 7-nitro-5-sulfo-napthalene-1,4- dicarboxylate acid

Rui Feng Wu, Tong Lai Zhang^*, Xiao Jing Qiao, Jian Guo Zhang, Li Yang, Wei Yu

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

The title compound (C₁₂H₁₅NO₁₃S, M _r = 413.31 ) was synthesized by the nitration of napthalene-1,4- dicarboxylate acid in mixed nitric and sulfuric acids. It crystallizes in monoclinic, space group P2₁/c with a = 8.100(1), b = 24.369(3), c = 8.634(1) Å β = 105.380(2)°, V = 1643.1(4) Å³, Z = 4, D_c = 1.671 g/cm³, F(000) = 856, μ(MoKα) = 0.273 mm^-1, T = 294(2) K, the final R = 0.0400 and wR = 0.1021 for 2866 observed reflections with I > 2σ(I). In this crystal there exist a number of H-bonds which link the molecules to form a three-dimensional infinite network structure. The thermal decomposition of the title compound was investigated by using TG-DTG and DSC techniques.

Original language	English
Pages (from-to)	849-853
Number of pages	5
Journal	Jiegou Huaxue
Volume	25
Issue number	7
Publication status	Published - 2006

Keywords

7-nitro-5-sulfo-napthalene-1,4-dicarboxylate acid
Crystal structure
Thermal analysis

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@article{3a5bfe2a2e5a49b2bf1450c3882c7d76,

title = "Synthesis and crystal structure of 7-nitro-5-sulfo-napthalene-1,4- dicarboxylate acid",

abstract = "The title compound (C12H15NO13S, M r = 413.31 ) was synthesized by the nitration of napthalene-1,4- dicarboxylate acid in mixed nitric and sulfuric acids. It crystallizes in monoclinic, space group P21/c with a = 8.100(1), b = 24.369(3), c = 8.634(1) {\AA} β = 105.380(2)°, V = 1643.1(4) {\AA}3, Z = 4, Dc = 1.671 g/cm3, F(000) = 856, μ(MoKα) = 0.273 mm-1, T = 294(2) K, the final R = 0.0400 and wR = 0.1021 for 2866 observed reflections with I > 2σ(I). In this crystal there exist a number of H-bonds which link the molecules to form a three-dimensional infinite network structure. The thermal decomposition of the title compound was investigated by using TG-DTG and DSC techniques.",

keywords = "7-nitro-5-sulfo-napthalene-1,4-dicarboxylate acid, Crystal structure, Thermal analysis",

author = "Wu, {Rui Feng} and Zhang, {Tong Lai} and Qiao, {Xiao Jing} and Zhang, {Jian Guo} and Li Yang and Wei Yu",

year = "2006",

language = "English",

volume = "25",

pages = "849--853",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "7",

}

TY - JOUR

T1 - Synthesis and crystal structure of 7-nitro-5-sulfo-napthalene-1,4- dicarboxylate acid

AU - Wu, Rui Feng

AU - Zhang, Tong Lai

AU - Qiao, Xiao Jing

AU - Zhang, Jian Guo

AU - Yang, Li

AU - Yu, Wei

PY - 2006

Y1 - 2006

N2 - The title compound (C12H15NO13S, M r = 413.31 ) was synthesized by the nitration of napthalene-1,4- dicarboxylate acid in mixed nitric and sulfuric acids. It crystallizes in monoclinic, space group P21/c with a = 8.100(1), b = 24.369(3), c = 8.634(1) Å β = 105.380(2)°, V = 1643.1(4) Å3, Z = 4, Dc = 1.671 g/cm3, F(000) = 856, μ(MoKα) = 0.273 mm-1, T = 294(2) K, the final R = 0.0400 and wR = 0.1021 for 2866 observed reflections with I > 2σ(I). In this crystal there exist a number of H-bonds which link the molecules to form a three-dimensional infinite network structure. The thermal decomposition of the title compound was investigated by using TG-DTG and DSC techniques.

AB - The title compound (C12H15NO13S, M r = 413.31 ) was synthesized by the nitration of napthalene-1,4- dicarboxylate acid in mixed nitric and sulfuric acids. It crystallizes in monoclinic, space group P21/c with a = 8.100(1), b = 24.369(3), c = 8.634(1) Å β = 105.380(2)°, V = 1643.1(4) Å3, Z = 4, Dc = 1.671 g/cm3, F(000) = 856, μ(MoKα) = 0.273 mm-1, T = 294(2) K, the final R = 0.0400 and wR = 0.1021 for 2866 observed reflections with I > 2σ(I). In this crystal there exist a number of H-bonds which link the molecules to form a three-dimensional infinite network structure. The thermal decomposition of the title compound was investigated by using TG-DTG and DSC techniques.

KW - 7-nitro-5-sulfo-napthalene-1,4-dicarboxylate acid

KW - Crystal structure

KW - Thermal analysis

UR - http://www.scopus.com/inward/record.url?scp=33746649071&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33746649071

SN - 0254-5861

VL - 25

SP - 849

EP - 853

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 7

ER -

Synthesis and crystal structure of 7-nitro-5-sulfo-napthalene-1,4- dicarboxylate acid

Abstract

Keywords

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