Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1039/b402321h

Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

A new inorganic-organic hybrid solid, Ni(DETA)(H₂O)Zn ₂(HPO₃)₃ (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO₄ and HPO₃ polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni₂(DETA)₂(H₂O) ₂O₂ dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

Original language	English
Pages (from-to)	1652-1655
Number of pages	4
Journal	Journal of Materials Chemistry
Volume	14
Issue number	10
DOIs	https://doi.org/10.1039/b402321h
Publication status	Published - 21 May 2004
Externally published	Yes

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title = "Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels",

abstract = "A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn 2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O) 2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.",

author = "Lin, {Zhi En} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

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AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/5/21

Y1 - 2004/5/21

N2 - A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn 2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O) 2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

AB - A new inorganic-organic hybrid solid, Ni(DETA)(H2O)Zn 2(HPO3)3 (FJ-14), has been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction, thermogravimetric analysis and magnetic susceptibility measurements. The compound is novel in the sense that it represents the first example of open- framework bimetallic phosphite. The structure of the compound consists of strictly alternating ZnO4 and HPO3 polyhedra through their vertices, forming zinc phosphite layers parallel to the bc plane. These layers are further pillared by Ni2(DETA)2(H2O) 2O2 dinuclear units to generate a 3D framework with intersecting three-dimensional 16-ring channels.

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ER -

Synthesis and characterization of a novel open-framework nickel-zinc phosphite with intersecting three-dimensional 16-ring channels

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