TY - JOUR
T1 - Study on one-dimensional chain coordination polymer [Cd(1,3,5- benzenetricarboxylate)(pyridine)3] n
T2 - Diffusion synthesis, crystal structure, and thermal analyses
AU - Guo, Jinyu
AU - Zhang, Tonglai
AU - Zhang, Jianguo
AU - Liu, Yanhong
AU - Yu, Wei
AU - Wu, Ruifeng
PY - 2006/12
Y1 - 2006/12
N2 - The crystal of the coordination polymer [Cd(1,3,5-btc)(py)3] n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG-DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.
AB - The crystal of the coordination polymer [Cd(1,3,5-btc)(py)3] n (1; 1,3,5-btc: 1,3,5-benzenetricar- boxylate; py: pyridine) has been synthesized, cultured by diffusion method, and characterized by X-ray single crystal diffraction, elemental analysis, and FTIR spectroscopy. In 1,3,5-benzenetricarboxylates with two kinds of coordination styles as bridging ligands, the cadmium(III) centers are linked together to form one-dimensional molecular chains. Thermal decomposition mechanisms were predicted on the basis of TG-DTG curve and FTIR spectra of the chain coordination polymer. Kinetic equations of the second and third mass loss stages were determined from the DTG curve using integral and differential methods.
KW - 1,3,5-benzenetricarboxylic acid
KW - Chain coordination polymer
KW - Crystal structure
KW - Non-isothermal kinetics
KW - Thermal decomposition mechanism
UR - http://www.scopus.com/inward/record.url?scp=33845489437&partnerID=8YFLogxK
U2 - 10.1007/s11224-006-9075-4
DO - 10.1007/s11224-006-9075-4
M3 - Article
AN - SCOPUS:33845489437
SN - 1040-0400
VL - 17
SP - 577
EP - 583
JO - Structural Chemistry
JF - Structural Chemistry
IS - 6
ER -