Study on kinetics of the VNS amination of 4-amino-1,2,4-triazole and 2,4,6-trinitromethylbenzene by HPLC

Si Yao Jiang; Yu Kai Wu; Ji Nan Li; Yan Xia Zhou; Zhi Ming Zhou

Study on kinetics of the VNS amination of 4-amino-1,2,4-triazole and 2,4,6-trinitromethylbenzene by HPLC

Si Yao Jiang^*, Yu Kai Wu, Ji Nan Li, Yan Xia Zhou, Zhi Ming Zhou

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The kinetic model of the VNS amination reaction of 2,4,6- trinitromethylbenzene(TNT) and 4-amino-1, 2,4-triazole(ATA) was investigated by monitoring the change of concentrations of reactant with time using HPLC method, the rate constants and activation energy of the reaction were obtained. The experimental results showed that study on kinetics of the VNS amination by HPLC was available. The rate constants at 25°C and 35°C are 0. 36 L · mol^-1 · min^-1 and 0. 63L · mol^-1 · min^-1, respectively. The activation energy of the reaction was 42. 74 kJ · mol^-1. The reaction is easy to process, and with the increase of temperature, the rate constant increases.

Original language	English
Pages (from-to)	22-24
Number of pages	3
Journal	Huozhayao Xuebao/Chinese Journal of Explosives and Propellants
Volume	33
Issue number	2
Publication status	Published - 2010

Keywords

HPLC
Physical chemistry
Reaction kinetics
VNS amination reaction

Cite this

@article{1089590c06e44baab14f42d27600eb9b,

title = "Study on kinetics of the VNS amination of 4-amino-1,2,4-triazole and 2,4,6-trinitromethylbenzene by HPLC",

abstract = "The kinetic model of the VNS amination reaction of 2,4,6- trinitromethylbenzene(TNT) and 4-amino-1, 2,4-triazole(ATA) was investigated by monitoring the change of concentrations of reactant with time using HPLC method, the rate constants and activation energy of the reaction were obtained. The experimental results showed that study on kinetics of the VNS amination by HPLC was available. The rate constants at 25°C and 35°C are 0. 36 L · mol-1 · min-1 and 0. 63L · mol-1 · min-1, respectively. The activation energy of the reaction was 42. 74 kJ · mol-1. The reaction is easy to process, and with the increase of temperature, the rate constant increases.",

keywords = "HPLC, Physical chemistry, Reaction kinetics, VNS amination reaction",

author = "Jiang, {Si Yao} and Wu, {Yu Kai} and Li, {Ji Nan} and Zhou, {Yan Xia} and Zhou, {Zhi Ming}",

year = "2010",

language = "English",

volume = "33",

pages = "22--24",

journal = "Huozhayao Xuebao/Chinese Journal of Explosives and Propellants",

issn = "1007-7812",

publisher = "China Ordnance Industry Corporation",

number = "2",

}

TY - JOUR

T1 - Study on kinetics of the VNS amination of 4-amino-1,2,4-triazole and 2,4,6-trinitromethylbenzene by HPLC

AU - Jiang, Si Yao

AU - Wu, Yu Kai

AU - Li, Ji Nan

AU - Zhou, Yan Xia

AU - Zhou, Zhi Ming

PY - 2010

Y1 - 2010

N2 - The kinetic model of the VNS amination reaction of 2,4,6- trinitromethylbenzene(TNT) and 4-amino-1, 2,4-triazole(ATA) was investigated by monitoring the change of concentrations of reactant with time using HPLC method, the rate constants and activation energy of the reaction were obtained. The experimental results showed that study on kinetics of the VNS amination by HPLC was available. The rate constants at 25°C and 35°C are 0. 36 L · mol-1 · min-1 and 0. 63L · mol-1 · min-1, respectively. The activation energy of the reaction was 42. 74 kJ · mol-1. The reaction is easy to process, and with the increase of temperature, the rate constant increases.

AB - The kinetic model of the VNS amination reaction of 2,4,6- trinitromethylbenzene(TNT) and 4-amino-1, 2,4-triazole(ATA) was investigated by monitoring the change of concentrations of reactant with time using HPLC method, the rate constants and activation energy of the reaction were obtained. The experimental results showed that study on kinetics of the VNS amination by HPLC was available. The rate constants at 25°C and 35°C are 0. 36 L · mol-1 · min-1 and 0. 63L · mol-1 · min-1, respectively. The activation energy of the reaction was 42. 74 kJ · mol-1. The reaction is easy to process, and with the increase of temperature, the rate constant increases.

KW - HPLC

KW - Physical chemistry

KW - Reaction kinetics

KW - VNS amination reaction

UR - http://www.scopus.com/inward/record.url?scp=77955482253&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:77955482253

SN - 1007-7812

VL - 33

SP - 22

EP - 24

JO - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

JF - Huozhayao Xuebao/Chinese Journal of Explosives and Propellants

IS - 2

ER -

Study on kinetics of the VNS amination of 4-amino-1,2,4-triazole and 2,4,6-trinitromethylbenzene by HPLC

Abstract

Keywords

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