Study on a series of main-chain liquid-crystalline ionomers containing sulfonate groups

Junge Zhi, Baoyan Zhang*, Yanying Wu, Zhiliu Feng

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Citations (Scopus)

Abstract

A series of main-chain liquid-crystalline ionomers containing sulfonate groups pendant on the polymer backbone were synthesized by an interfacial condensation reaction of 4,4′-dihydroxy-α,α′-dimethyl benzalazine, a mesogenic monomer, with brilliant yellow (BY), a sulfonate-containing monomer, and a 1/9 mixture of terephthaloyl and sebacoyl dichloride. The structures of the polymers were characterized by IR and UV spectroscopies. DSC and thermogravimetric analysis were used to measure the thermal properties of those polymers, and the mesogenic properties were characterized by a polarized optical microscope, DSC, and wide-angle X-ray diffraction. The ionomers were thermally stable to about 310°C. They were thermotropic liquid-crystalline polymers (LCPs) with high mesomorphic-phase transition temperatures and exhibited broad nematic mesogenic regions of 160-170°C, and they were lyotropic LCPs with willowy leaf-shaped textures in sulphuric acid. However, the thermotropic liquid-crystalline properties were somewhat weakened because the concentration of BY was more than 8%. The inherent viscosity in N-methyl-2-pyrrolidone suggested that intramolecular associations of sulfonate groups occurred at low concentration, and intermolecular associations predominated at higher concentration.

Original languageEnglish
Pages (from-to)2210-2218
Number of pages9
JournalJournal of Applied Polymer Science
Volume81
Issue number9
DOIs
Publication statusPublished - 29 Aug 2001
Externally publishedYes

Keywords

  • DDBA
  • Lyotropic
  • Main-chain liquid-crystalline ionomer
  • Sulfonate group
  • Thermotropic

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