Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

Miao Miao Xiao; Bin Tong; Wei Zhao; Jian Bing Shi; Yue Xiu Pan; Jin Bo Shen; Jun Ge Zhi; Yu Ping Dong

doi:10.1007/s10118-010-9014-0

Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

Miao Miao Xiao, Bin Tong, Wei Zhao, Jian Bing Shi, Yue Xiu Pan, Jin Bo Shen, Jun Ge Zhi, Yu Ping Dong^*

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

6 Citations (Scopus)

Abstract

The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

Original language	English
Pages (from-to)	331-336
Number of pages	6
Journal	Chinese Journal of Polymer Science (English Edition)
Volume	28
Issue number	3
DOIs	https://doi.org/10.1007/s10118-010-9014-0
Publication status	Published - May 2010

Keywords

Electrochemical Properties
Film-CdS composites
Polyanilines
Self-assembly multilayer films

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10.1007/s10118-010-9014-0

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title = "Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates",

abstract = "The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.",

keywords = "Electrochemical Properties, Film-CdS composites, Polyanilines, Self-assembly multilayer films",

author = "Xiao, {Miao Miao} and Bin Tong and Wei Zhao and Shi, {Jian Bing} and Pan, {Yue Xiu} and Shen, {Jin Bo} and Zhi, {Jun Ge} and Dong, {Yu Ping}",

year = "2010",

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doi = "10.1007/s10118-010-9014-0",

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T1 - Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

AU - Xiao, Miao Miao

AU - Tong, Bin

AU - Zhao, Wei

AU - Shi, Jian Bing

AU - Pan, Yue Xiu

AU - Shen, Jin Bo

AU - Zhi, Jun Ge

AU - Dong, Yu Ping

PY - 2010/5

Y1 - 2010/5

N2 - The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

AB - The stability of full-conjugated self-assembled (SA) multilayer films based on partially doped polyaniline (PANI) as a polycation and poly(o-aminobenzoic acid) (PCAN), poly(aniline-2-sulfonic acid) (PSAN) as polyanions is investigated in alkali aqueous solutions. The self-assembled PANI-PCAN films keep their stability within 24 h in 1 mol/L NaOH solution, -the PANI-PSAN films, however, maintain the stability for 20 min in the same condition because the solubility of PSAN in alkali solutions is much higher than that of PCAN. The electrochemical properties of the SA films are determined, and the film-CdS composites formed in situ are also reported.

KW - Electrochemical Properties

KW - Film-CdS composites

KW - Polyanilines

KW - Self-assembly multilayer films

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U2 - 10.1007/s10118-010-9014-0

DO - 10.1007/s10118-010-9014-0

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SN - 0256-7679

VL - 28

SP - 331

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JO - Chinese Journal of Polymer Science (English Edition)

JF - Chinese Journal of Polymer Science (English Edition)

IS - 3

ER -

Stability and electrochemical properties of full-conjugated self-assembled films based on polyaniline and its acid-substituted derivates

Abstract

Keywords

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