Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation

Xiao Mei Wei; Yong Fang Qi; Sheng Li Huang; Guo Yu Yang

doi:10.1002/ejic.202200204

Ru(N^N)₃-Metalloligand Pillared Zr₆-Organic Layers for Aerobic Photooxidation

Xiao Mei Wei, Yong Fang Qi, Sheng Li Huang^*, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The stable Zr₆-based coordination framework Ru-1 was assembled via the linkage of Zr₆-organic layers and photosensitized Ru(N^N)₃-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)₃-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.

Original language	English
Article number	e202200204
Journal	European Journal of Inorganic Chemistry
Volume	2022
Issue number	20
DOIs	https://doi.org/10.1002/ejic.202200204
Publication status	Published - 19 Jul 2022

Keywords

Photocatalysis
Photooxidation
Reactive oxygen species
Ru(N^N)-metalloligand
Ru-photosensitizer

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10.1002/ejic.202200204

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title = "Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation",

abstract = "The stable Zr6-based coordination framework Ru-1 was assembled via the linkage of Zr6-organic layers and photosensitized Ru(N^N)3-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)3-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.",

keywords = "Photocatalysis, Photooxidation, Reactive oxygen species, Ru(N^N)-metalloligand, Ru-photosensitizer",

author = "Wei, {Xiao Mei} and Qi, {Yong Fang} and Huang, {Sheng Li} and Yang, {Guo Yu}",

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doi = "10.1002/ejic.202200204",

language = "English",

volume = "2022",

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T1 - Ru(N^N)3-Metalloligand Pillared Zr6-Organic Layers for Aerobic Photooxidation

AU - Wei, Xiao Mei

AU - Qi, Yong Fang

AU - Huang, Sheng Li

AU - Yang, Guo Yu

PY - 2022/7/19

Y1 - 2022/7/19

N2 - The stable Zr6-based coordination framework Ru-1 was assembled via the linkage of Zr6-organic layers and photosensitized Ru(N^N)3-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)3-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.

AB - The stable Zr6-based coordination framework Ru-1 was assembled via the linkage of Zr6-organic layers and photosensitized Ru(N^N)3-metalloligand. Based on its 1D open channel and the incorporation of Ru(N^N)3-photosensitizer, it can serve as a highly efficient heterogeneous catalyst in the aerobic photooxidation reactions, including photooxidation of sulfides, coupling of amines and oxidative hydroxylation of arylboronic acids. The stability and catalytic performance of recycled Ru-1 was also explored.

KW - Photocatalysis

KW - Photooxidation

KW - Reactive oxygen species

KW - Ru(N^N)-metalloligand

KW - Ru-photosensitizer

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DO - 10.1002/ejic.202200204

M3 - Article

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SN - 1434-1948

VL - 2022

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 20

M1 - e202200204

ER -

Ru(N^N)₃-Metalloligand Pillared Zr₆-Organic Layers for Aerobic Photooxidation

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Keywords

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