Ring-shaped polyoxometalate built by {Mn4PW9} and PO4 units for efficient visible-light-driven hydrogen evolution

Hai Lou Li; Mo Zhang; Chen Lian; Zhong Ling Lang; Hongjin Lv; Guo Yu Yang

doi:10.31635/ccschem.020.202000403

Ring-shaped polyoxometalate built by {Mn₄PW₉} and PO₄ units for efficient visible-light-driven hydrogen evolution

Hai Lou Li, Mo Zhang, Chen Lian, Zhong Ling Lang^*, Hongjin Lv^*, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

50 Citations (Scopus)

Abstract

A novel mixed-valence, ring-shaped multinuclear Mn-containing polyoxometalate, [H₂N(CH₃)₂]₁₅ NaH₈-[Mn^III₃Mn^IV(μ₃-O)₃(OAc)PO₄(B-α-PW₉O₃₄)]₄· 36H₂O (1) was made and systematically characterized using various spectroscopic and computational techniques. Its polyoxoanion can be described as a tetramer made of four [Mn^III₃Mn^IV(μ₃-O)₃(OAc) (B-α-PW₉O₃₄)]³⁻ ({Mn^III₃Mn^IV(PW₉)}) clusters and four PO₄ linkers. Significantly, this structurally new complex 1 can efficiently catalyze hydrogen evolution with 23 μmol H₂ gas after 12 h of visible-light irradiation using a three-component system. We propose a possible catalytic hydrogen-evolving mechanism based on both experimental results and density functional theory (DFT) calculations.

Original language	English
Pages (from-to)	2095
Number of pages	1
Journal	CCS Chemistry
Volume	3
Issue number	8
DOIs	https://doi.org/10.31635/ccschem.020.202000403
Publication status	Published - Aug 2021

Keywords

Hydrogen evolution
Polynuclear manganese clusters
Polyoxometalates
Visible-light irradiation

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@article{9490db2816a34cf8ad5828d5bc1eb666,

title = "Ring-shaped polyoxometalate built by {Mn4PW9} and PO4 units for efficient visible-light-driven hydrogen evolution",

abstract = "A novel mixed-valence, ring-shaped multinuclear Mn-containing polyoxometalate, [H2N(CH3)2]15 NaH8-[MnIII3MnIV(μ3-O)3(OAc)PO4(B-α-PW9O34)]4· 36H2O (1) was made and systematically characterized using various spectroscopic and computational techniques. Its polyoxoanion can be described as a tetramer made of four [MnIII3MnIV(μ3-O)3(OAc) (B-α-PW9O34)]3− ({MnIII3MnIV(PW9)}) clusters and four PO4 linkers. Significantly, this structurally new complex 1 can efficiently catalyze hydrogen evolution with 23 μmol H2 gas after 12 h of visible-light irradiation using a three-component system. We propose a possible catalytic hydrogen-evolving mechanism based on both experimental results and density functional theory (DFT) calculations.",

keywords = "Hydrogen evolution, Polynuclear manganese clusters, Polyoxometalates, Visible-light irradiation",

author = "Li, {Hai Lou} and Mo Zhang and Chen Lian and Lang, {Zhong Ling} and Hongjin Lv and Yang, {Guo Yu}",

year = "2021",

month = aug,

doi = "10.31635/ccschem.020.202000403",

language = "English",

volume = "3",

pages = "2095",

journal = "CCS Chemistry",

issn = "2096-5745",

publisher = "Chinese Chemical Society",

number = "8",

}

TY - JOUR

T1 - Ring-shaped polyoxometalate built by {Mn4PW9} and PO4 units for efficient visible-light-driven hydrogen evolution

AU - Li, Hai Lou

AU - Zhang, Mo

AU - Lian, Chen

AU - Lang, Zhong Ling

AU - Lv, Hongjin

AU - Yang, Guo Yu

PY - 2021/8

Y1 - 2021/8

N2 - A novel mixed-valence, ring-shaped multinuclear Mn-containing polyoxometalate, [H2N(CH3)2]15 NaH8-[MnIII3MnIV(μ3-O)3(OAc)PO4(B-α-PW9O34)]4· 36H2O (1) was made and systematically characterized using various spectroscopic and computational techniques. Its polyoxoanion can be described as a tetramer made of four [MnIII3MnIV(μ3-O)3(OAc) (B-α-PW9O34)]3− ({MnIII3MnIV(PW9)}) clusters and four PO4 linkers. Significantly, this structurally new complex 1 can efficiently catalyze hydrogen evolution with 23 μmol H2 gas after 12 h of visible-light irradiation using a three-component system. We propose a possible catalytic hydrogen-evolving mechanism based on both experimental results and density functional theory (DFT) calculations.

AB - A novel mixed-valence, ring-shaped multinuclear Mn-containing polyoxometalate, [H2N(CH3)2]15 NaH8-[MnIII3MnIV(μ3-O)3(OAc)PO4(B-α-PW9O34)]4· 36H2O (1) was made and systematically characterized using various spectroscopic and computational techniques. Its polyoxoanion can be described as a tetramer made of four [MnIII3MnIV(μ3-O)3(OAc) (B-α-PW9O34)]3− ({MnIII3MnIV(PW9)}) clusters and four PO4 linkers. Significantly, this structurally new complex 1 can efficiently catalyze hydrogen evolution with 23 μmol H2 gas after 12 h of visible-light irradiation using a three-component system. We propose a possible catalytic hydrogen-evolving mechanism based on both experimental results and density functional theory (DFT) calculations.

KW - Hydrogen evolution

KW - Polynuclear manganese clusters

KW - Polyoxometalates

KW - Visible-light irradiation

UR - http://www.scopus.com/inward/record.url?scp=85103496496&partnerID=8YFLogxK

U2 - 10.31635/ccschem.020.202000403

DO - 10.31635/ccschem.020.202000403

M3 - Article

AN - SCOPUS:85103496496

SN - 2096-5745

VL - 3

SP - 2095

JO - CCS Chemistry

JF - CCS Chemistry

IS - 8

ER -

Ring-shaped polyoxometalate built by {Mn₄PW₉} and PO₄ units for efficient visible-light-driven hydrogen evolution

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Keywords

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