Researches on thermal decomposition kinetics of composite modified double-base propellants

Zhan Tang; Yan Ren; Li Yang; Tonglai Zhang; Xiaojing Qiao; Jianguo Zhang; Zunning Zhou; Fengqi Zhao; Yongzhan Dang; Siyu Xu; Jianhua Yi

doi:10.1002/cjoc.201190096

Researches on thermal decomposition kinetics of composite modified double-base propellants

Zhan Tang^*, Yan Ren, Li Yang, Tonglai Zhang, Xiaojing Qiao, Jianguo Zhang, Zunning Zhou, Fengqi Zhao, Yongzhan Dang, Siyu Xu, Jianhua Yi

^*Corresponding author for this work

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

The thermal decomposition kinetics of composite modified double-base (CMDB) propellants with a series of contents of hexogeon (RDX) was investigated by using parameters of T_eo, T_i, T_p, T_f, T_b, T_a, E, lg A and ΔH, which were obtained from using a CDR-4P differential scanning calorimeter (DSC) and Perkin-Elmer Pyris 1 thermogravimetric analyzer (TG) analyses with heating rates of 5, 10, 15 and 20 K/min. Reliable activation energy was calculated using Flynn-Wall-Ozawa method before analyzing the thermal decomposition mechanism. TG-DTG curves were treated with Malek method in order to obtain the reaction mechanisms. The obtained results show that the thermal decomposition mechanisms with the conversion from 0.2 to 0.4 was f(α) 1/2α, and with the conversion from 0.5 to 0.7 was f(α)=(1/4)(1-α)[-ln(1-α)]^-3.

Original language	English
Pages (from-to)	411-414
Number of pages	4
Journal	Chinese Journal of Chemistry
Volume	29
Issue number	3
DOIs	https://doi.org/10.1002/cjoc.201190096
Publication status	Published - Mar 2011

Keywords

DSC
Decomposition machenism
Malek method
TG
Thermal stability

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10.1002/cjoc.201190096

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title = "Researches on thermal decomposition kinetics of composite modified double-base propellants",

abstract = "The thermal decomposition kinetics of composite modified double-base (CMDB) propellants with a series of contents of hexogeon (RDX) was investigated by using parameters of Teo, Ti, Tp, Tf, Tb, Ta, E, lg A and ΔH, which were obtained from using a CDR-4P differential scanning calorimeter (DSC) and Perkin-Elmer Pyris 1 thermogravimetric analyzer (TG) analyses with heating rates of 5, 10, 15 and 20 K/min. Reliable activation energy was calculated using Flynn-Wall-Ozawa method before analyzing the thermal decomposition mechanism. TG-DTG curves were treated with Malek method in order to obtain the reaction mechanisms. The obtained results show that the thermal decomposition mechanisms with the conversion from 0.2 to 0.4 was f(α) 1/2α, and with the conversion from 0.5 to 0.7 was f(α)=(1/4)(1-α)[-ln(1-α)]-3.",

keywords = "DSC, Decomposition machenism, Malek method, TG, Thermal stability",

author = "Zhan Tang and Yan Ren and Li Yang and Tonglai Zhang and Xiaojing Qiao and Jianguo Zhang and Zunning Zhou and Fengqi Zhao and Yongzhan Dang and Siyu Xu and Jianhua Yi",

year = "2011",

month = mar,

doi = "10.1002/cjoc.201190096",

language = "English",

volume = "29",

pages = "411--414",

journal = "Chinese Journal of Chemistry",

issn = "1001-604X",

publisher = "John Wiley and Sons Inc.",

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TY - JOUR

T1 - Researches on thermal decomposition kinetics of composite modified double-base propellants

AU - Tang, Zhan

AU - Ren, Yan

AU - Yang, Li

AU - Zhang, Tonglai

AU - Qiao, Xiaojing

AU - Zhang, Jianguo

AU - Zhou, Zunning

AU - Zhao, Fengqi

AU - Dang, Yongzhan

AU - Xu, Siyu

AU - Yi, Jianhua

PY - 2011/3

Y1 - 2011/3

N2 - The thermal decomposition kinetics of composite modified double-base (CMDB) propellants with a series of contents of hexogeon (RDX) was investigated by using parameters of Teo, Ti, Tp, Tf, Tb, Ta, E, lg A and ΔH, which were obtained from using a CDR-4P differential scanning calorimeter (DSC) and Perkin-Elmer Pyris 1 thermogravimetric analyzer (TG) analyses with heating rates of 5, 10, 15 and 20 K/min. Reliable activation energy was calculated using Flynn-Wall-Ozawa method before analyzing the thermal decomposition mechanism. TG-DTG curves were treated with Malek method in order to obtain the reaction mechanisms. The obtained results show that the thermal decomposition mechanisms with the conversion from 0.2 to 0.4 was f(α) 1/2α, and with the conversion from 0.5 to 0.7 was f(α)=(1/4)(1-α)[-ln(1-α)]-3.

AB - The thermal decomposition kinetics of composite modified double-base (CMDB) propellants with a series of contents of hexogeon (RDX) was investigated by using parameters of Teo, Ti, Tp, Tf, Tb, Ta, E, lg A and ΔH, which were obtained from using a CDR-4P differential scanning calorimeter (DSC) and Perkin-Elmer Pyris 1 thermogravimetric analyzer (TG) analyses with heating rates of 5, 10, 15 and 20 K/min. Reliable activation energy was calculated using Flynn-Wall-Ozawa method before analyzing the thermal decomposition mechanism. TG-DTG curves were treated with Malek method in order to obtain the reaction mechanisms. The obtained results show that the thermal decomposition mechanisms with the conversion from 0.2 to 0.4 was f(α) 1/2α, and with the conversion from 0.5 to 0.7 was f(α)=(1/4)(1-α)[-ln(1-α)]-3.

KW - DSC

KW - Decomposition machenism

KW - Malek method

KW - TG

KW - Thermal stability

UR - http://www.scopus.com/inward/record.url?scp=79953236570&partnerID=8YFLogxK

U2 - 10.1002/cjoc.201190096

DO - 10.1002/cjoc.201190096

M3 - Article

AN - SCOPUS:79953236570

SN - 1001-604X

VL - 29

SP - 411

EP - 414

JO - Chinese Journal of Chemistry

JF - Chinese Journal of Chemistry

IS - 3

ER -

Researches on thermal decomposition kinetics of composite modified double-base propellants

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Keywords

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