Relationship between lattice energy and sensitivity of [M(CHZ)3](NO3)2 and [M(CHZ)3] (ClO4)2 (M =Mn, Zn, Ni)

Qiu Yu Zheng; Xiao Jing Qiao; Feng Lei Shao; Jian Guo Zhang; Li Yang

Relationship between lattice energy and sensitivity of [M(CHZ)₃](NO₃)₂ and [M(CHZ)₃] (ClO₄)₂ (M =Mn, Zn, Ni)

Qiu Yu Zheng, Xiao Jing Qiao^*, Feng Lei Shao, Jian Guo Zhang, Li Yang

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The standard molar enthalpies of series of energetic coordination compounds solution with carbohydrazide as ligand and nitrate or perchlorate as anion in deionized water were measured by a Setaram C80II microcalorimeter at 298.15K. Based on these values, their lattice energy were calculated through Kapustinkii formula, meanwhile the thermochemistry radius of [M(CHZ)₃]²⁺ (M = Mn, Zn, Ni) was gained. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. Results show that the lattice energy of perchlorate are smaller than their corresponding nitrate, thus the perchlorate are more sensitive.

Original language	English
Pages (from-to)	198-201
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	17
Issue number	2
Publication status	Published - Apr 2009

Keywords

Enthalpy of solution
Lattice energy
Physical chemistry
Sensitivity
[M (CHZ)] (ClO) (M= Mn, Zn, Ni)
[M(CHZ)] (NO)

Cite this

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title = "Relationship between lattice energy and sensitivity of [M(CHZ)3](NO3)2 and [M(CHZ)3] (ClO4)2 (M =Mn, Zn, Ni)",

abstract = "The standard molar enthalpies of series of energetic coordination compounds solution with carbohydrazide as ligand and nitrate or perchlorate as anion in deionized water were measured by a Setaram C80II microcalorimeter at 298.15K. Based on these values, their lattice energy were calculated through Kapustinkii formula, meanwhile the thermochemistry radius of [M(CHZ)3]2+ (M = Mn, Zn, Ni) was gained. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. Results show that the lattice energy of perchlorate are smaller than their corresponding nitrate, thus the perchlorate are more sensitive.",

keywords = "Enthalpy of solution, Lattice energy, Physical chemistry, Sensitivity, [M (CHZ)] (ClO) (M= Mn, Zn, Ni), [M(CHZ)] (NO)",

author = "Zheng, {Qiu Yu} and Qiao, {Xiao Jing} and Shao, {Feng Lei} and Zhang, {Jian Guo} and Li Yang",

year = "2009",

month = apr,

language = "English",

volume = "17",

pages = "198--201",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

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TY - JOUR

T1 - Relationship between lattice energy and sensitivity of [M(CHZ)3](NO3)2 and [M(CHZ)3] (ClO4)2 (M =Mn, Zn, Ni)

AU - Zheng, Qiu Yu

AU - Qiao, Xiao Jing

AU - Shao, Feng Lei

AU - Zhang, Jian Guo

AU - Yang, Li

PY - 2009/4

Y1 - 2009/4

N2 - The standard molar enthalpies of series of energetic coordination compounds solution with carbohydrazide as ligand and nitrate or perchlorate as anion in deionized water were measured by a Setaram C80II microcalorimeter at 298.15K. Based on these values, their lattice energy were calculated through Kapustinkii formula, meanwhile the thermochemistry radius of [M(CHZ)3]2+ (M = Mn, Zn, Ni) was gained. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. Results show that the lattice energy of perchlorate are smaller than their corresponding nitrate, thus the perchlorate are more sensitive.

AB - The standard molar enthalpies of series of energetic coordination compounds solution with carbohydrazide as ligand and nitrate or perchlorate as anion in deionized water were measured by a Setaram C80II microcalorimeter at 298.15K. Based on these values, their lattice energy were calculated through Kapustinkii formula, meanwhile the thermochemistry radius of [M(CHZ)3]2+ (M = Mn, Zn, Ni) was gained. The relationship between lattice energy and impact sensitivity or friction sensitivity was discussed. Results show that the lattice energy of perchlorate are smaller than their corresponding nitrate, thus the perchlorate are more sensitive.

KW - Enthalpy of solution

KW - Lattice energy

KW - Physical chemistry

KW - Sensitivity

KW - [M (CHZ)] (ClO) (M= Mn, Zn, Ni)

KW - [M(CHZ)] (NO)

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M3 - Article

AN - SCOPUS:66149186724

SN - 1006-9941

VL - 17

SP - 198

EP - 201

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 2

ER -

Relationship between lattice energy and sensitivity of [M(CHZ)₃](NO₃)₂ and [M(CHZ)₃] (ClO₄)₂ (M =Mn, Zn, Ni)

Abstract

Keywords

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