Reductive linear- and cyclo-trimerization of isocyanides using an Al-Al-bonded compound

Weixing Chen; Yanxia Zhao; Wenhua Xu; Ji Hu Su; Lingyi Shen; Li Liu; Biao Wu; Xiao Juan Yang

doi:10.1039/c9cc04344f

Reductive linear- and cyclo-trimerization of isocyanides using an Al-Al-bonded compound

Weixing Chen, Yanxia Zhao^*, Wenhua Xu, Ji Hu Su, Lingyi Shen, Li Liu, Biao Wu, Xiao Juan Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

Dialumane 1 reacts with tBuNC to produce a reductive dimerization adduct [LAl(tBuNC-CNtBu)AlL] (2). In the presence of Na, 1 can promote linear- and cyclo-trimerization of isocyanides, affording products [Na][LAl{(tBuNC)₃}AlL] (3 and 4) and [Na][LAl{(tBuNC)₃}Al(CN)L] (5), the latter of which features a unique aromatic tri(tert-butylimino)deltate dianion [C₃N₃(tBu)₃]^2-.

Original language	English
Pages (from-to)	9452-9455
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	64
DOIs	https://doi.org/10.1039/c9cc04344f
Publication status	Published - 2019
Externally published	Yes

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title = "Reductive linear- and cyclo-trimerization of isocyanides using an Al-Al-bonded compound",

abstract = "Dialumane 1 reacts with tBuNC to produce a reductive dimerization adduct [LAl(tBuNC-CNtBu)AlL] (2). In the presence of Na, 1 can promote linear- and cyclo-trimerization of isocyanides, affording products [Na][LAl{(tBuNC)3}AlL] (3 and 4) and [Na][LAl{(tBuNC)3}Al(CN)L] (5), the latter of which features a unique aromatic tri(tert-butylimino)deltate dianion [C3N3(tBu)3]2-.",

author = "Weixing Chen and Yanxia Zhao and Wenhua Xu and Su, {Ji Hu} and Lingyi Shen and Li Liu and Biao Wu and Yang, {Xiao Juan}",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9cc04344f",

language = "English",

volume = "55",

pages = "9452--9455",

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T1 - Reductive linear- and cyclo-trimerization of isocyanides using an Al-Al-bonded compound

AU - Chen, Weixing

AU - Zhao, Yanxia

AU - Xu, Wenhua

AU - Su, Ji Hu

AU - Shen, Lingyi

AU - Liu, Li

AU - Wu, Biao

AU - Yang, Xiao Juan

PY - 2019

Y1 - 2019

N2 - Dialumane 1 reacts with tBuNC to produce a reductive dimerization adduct [LAl(tBuNC-CNtBu)AlL] (2). In the presence of Na, 1 can promote linear- and cyclo-trimerization of isocyanides, affording products [Na][LAl{(tBuNC)3}AlL] (3 and 4) and [Na][LAl{(tBuNC)3}Al(CN)L] (5), the latter of which features a unique aromatic tri(tert-butylimino)deltate dianion [C3N3(tBu)3]2-.

AB - Dialumane 1 reacts with tBuNC to produce a reductive dimerization adduct [LAl(tBuNC-CNtBu)AlL] (2). In the presence of Na, 1 can promote linear- and cyclo-trimerization of isocyanides, affording products [Na][LAl{(tBuNC)3}AlL] (3 and 4) and [Na][LAl{(tBuNC)3}Al(CN)L] (5), the latter of which features a unique aromatic tri(tert-butylimino)deltate dianion [C3N3(tBu)3]2-.

UR - http://www.scopus.com/inward/record.url?scp=85070450004&partnerID=8YFLogxK

U2 - 10.1039/c9cc04344f

DO - 10.1039/c9cc04344f

M3 - Article

C2 - 31322637

AN - SCOPUS:85070450004

SN - 1359-7345

VL - 55

SP - 9452

EP - 9455

JO - Chemical Communications

JF - Chemical Communications

IS - 64

ER -

Reductive linear- and cyclo-trimerization of isocyanides using an Al-Al-bonded compound

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