Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

Zhihui Ni; Hongjin Lv; Guoyu Yang

doi:10.3390/molecules27248799

Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

Zhihui Ni^*, Hongjin Lv^*, Guoyu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Zhongyuan University of Technology

Research output: Contribution to journal › Review article › peer-review

5 Citations (Scopus)

Abstract

Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have received considerable research attention due to their structural versatility and diverse physicochemical properties. Lacunary POMs are key building blocks for the syntheses of functional POMs due to their highly active multidentate O-donor sites. In this review, we have addressed the structural diversities of Ti/Zr-substituted POMs based on the polymerization number of POM building blocks and the number of Ti and Zr centers. The synthetic strategies and relevant catalytic applications of some representative Ti/Zr-substituted POMs have been discussed in detail. Finally, the outlook on the future development of this area is also prospected.

Original language	English
Article number	8799
Journal	Molecules
Volume	27
Issue number	24
DOIs	https://doi.org/10.3390/molecules27248799
Publication status	Published - Dec 2022

Keywords

polyoxometalates
titanium
transition metal substitution
zirconium

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10.3390/molecules27248799

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title = "Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications",

abstract = "Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have received considerable research attention due to their structural versatility and diverse physicochemical properties. Lacunary POMs are key building blocks for the syntheses of functional POMs due to their highly active multidentate O-donor sites. In this review, we have addressed the structural diversities of Ti/Zr-substituted POMs based on the polymerization number of POM building blocks and the number of Ti and Zr centers. The synthetic strategies and relevant catalytic applications of some representative Ti/Zr-substituted POMs have been discussed in detail. Finally, the outlook on the future development of this area is also prospected.",

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author = "Zhihui Ni and Hongjin Lv and Guoyu Yang",

note = "Publisher Copyright: {\textcopyright} 2022 by the authors.",

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month = dec,

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language = "English",

volume = "27",

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T1 - Recent Advances of Ti/Zr-Substituted Polyoxometalates

T2 - From Structural Diversity to Functional Applications

AU - Ni, Zhihui

AU - Lv, Hongjin

AU - Yang, Guoyu

PY - 2022/12

Y1 - 2022/12

N2 - Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have received considerable research attention due to their structural versatility and diverse physicochemical properties. Lacunary POMs are key building blocks for the syntheses of functional POMs due to their highly active multidentate O-donor sites. In this review, we have addressed the structural diversities of Ti/Zr-substituted POMs based on the polymerization number of POM building blocks and the number of Ti and Zr centers. The synthetic strategies and relevant catalytic applications of some representative Ti/Zr-substituted POMs have been discussed in detail. Finally, the outlook on the future development of this area is also prospected.

AB - Polyoxometalates (POMs), a large family of anionic polynuclear metal–oxo clusters, have received considerable research attention due to their structural versatility and diverse physicochemical properties. Lacunary POMs are key building blocks for the syntheses of functional POMs due to their highly active multidentate O-donor sites. In this review, we have addressed the structural diversities of Ti/Zr-substituted POMs based on the polymerization number of POM building blocks and the number of Ti and Zr centers. The synthetic strategies and relevant catalytic applications of some representative Ti/Zr-substituted POMs have been discussed in detail. Finally, the outlook on the future development of this area is also prospected.

KW - polyoxometalates

KW - titanium

KW - transition metal substitution

KW - zirconium

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U2 - 10.3390/molecules27248799

DO - 10.3390/molecules27248799

M3 - Review article

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SN - 1420-3049

VL - 27

JO - Molecules

JF - Molecules

IS - 24

M1 - 8799

ER -

Recent Advances of Ti/Zr-Substituted Polyoxometalates: From Structural Diversity to Functional Applications

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