Recent advances of mixed-transition-metal-substituted polyoxometalates

Zhimin Wang; Xing Xin; Mo Zhang; Zheng Li; Hongjin Lv; Guo Yu Yang

doi:10.1007/s11426-022-1276-4

Recent advances of mixed-transition-metal-substituted polyoxometalates

Zhimin Wang, Xing Xin, Mo Zhang, Zheng Li, Hongjin Lv^*, Guo Yu Yang^*

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Review article › peer-review

42 Citations (Scopus)

Abstract

Polyoxometalates (POMs) have been emerging as one of the most widely-studied interdisciplinary research fields of inorganic chemistry due to their structural diversities and versatile physicochemical properties. The incorporation of transition metals into lacunary POM ligands can lead to the formation of various transition-metal-substituted POMs (TMSPs) with wide potential applications in research areas including medicine, magnetism, functional materials, catalysis, and energy storage. In this review, we summarized the recent advances of mixed-transition-metal-substituted POMs (Mixed TMSPs) with respect to their synthetic strategies, structural diversities, and relevant applications. Finally, a comprehensive outlook of this research area was also prospected.[Figure not available: see fulltext.].

Original language	English
Pages (from-to)	1515-1525
Number of pages	11
Journal	Science China Chemistry
Volume	65
Issue number	8
DOIs	https://doi.org/10.1007/s11426-022-1276-4
Publication status	Published - Aug 2022

Keywords

catalysis
lacunary POM ligands
mixed-transition-metal substitution
polyoxometalates
structural diversity

Access to Document

10.1007/s11426-022-1276-4

Cite this

@article{a7943841869449fea1483281632abb2b,

title = "Recent advances of mixed-transition-metal-substituted polyoxometalates",

abstract = "Polyoxometalates (POMs) have been emerging as one of the most widely-studied interdisciplinary research fields of inorganic chemistry due to their structural diversities and versatile physicochemical properties. The incorporation of transition metals into lacunary POM ligands can lead to the formation of various transition-metal-substituted POMs (TMSPs) with wide potential applications in research areas including medicine, magnetism, functional materials, catalysis, and energy storage. In this review, we summarized the recent advances of mixed-transition-metal-substituted POMs (Mixed TMSPs) with respect to their synthetic strategies, structural diversities, and relevant applications. Finally, a comprehensive outlook of this research area was also prospected.[Figure not available: see fulltext.].",

keywords = "catalysis, lacunary POM ligands, mixed-transition-metal substitution, polyoxometalates, structural diversity",

author = "Zhimin Wang and Xing Xin and Mo Zhang and Zheng Li and Hongjin Lv and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} 2022, Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature.",

year = "2022",

month = aug,

doi = "10.1007/s11426-022-1276-4",

language = "English",

volume = "65",

pages = "1515--1525",

journal = "Science China Chemistry",

issn = "1674-7291",

publisher = "Science China Press",

number = "8",

}

TY - JOUR

T1 - Recent advances of mixed-transition-metal-substituted polyoxometalates

AU - Wang, Zhimin

AU - Xin, Xing

AU - Zhang, Mo

AU - Li, Zheng

AU - Lv, Hongjin

AU - Yang, Guo Yu

PY - 2022/8

Y1 - 2022/8

N2 - Polyoxometalates (POMs) have been emerging as one of the most widely-studied interdisciplinary research fields of inorganic chemistry due to their structural diversities and versatile physicochemical properties. The incorporation of transition metals into lacunary POM ligands can lead to the formation of various transition-metal-substituted POMs (TMSPs) with wide potential applications in research areas including medicine, magnetism, functional materials, catalysis, and energy storage. In this review, we summarized the recent advances of mixed-transition-metal-substituted POMs (Mixed TMSPs) with respect to their synthetic strategies, structural diversities, and relevant applications. Finally, a comprehensive outlook of this research area was also prospected.[Figure not available: see fulltext.].

AB - Polyoxometalates (POMs) have been emerging as one of the most widely-studied interdisciplinary research fields of inorganic chemistry due to their structural diversities and versatile physicochemical properties. The incorporation of transition metals into lacunary POM ligands can lead to the formation of various transition-metal-substituted POMs (TMSPs) with wide potential applications in research areas including medicine, magnetism, functional materials, catalysis, and energy storage. In this review, we summarized the recent advances of mixed-transition-metal-substituted POMs (Mixed TMSPs) with respect to their synthetic strategies, structural diversities, and relevant applications. Finally, a comprehensive outlook of this research area was also prospected.[Figure not available: see fulltext.].

KW - catalysis

KW - lacunary POM ligands

KW - mixed-transition-metal substitution

KW - polyoxometalates

KW - structural diversity

UR - http://www.scopus.com/inward/record.url?scp=85132428232&partnerID=8YFLogxK

U2 - 10.1007/s11426-022-1276-4

DO - 10.1007/s11426-022-1276-4

M3 - Review article

AN - SCOPUS:85132428232

SN - 1674-7291

VL - 65

SP - 1515

EP - 1525

JO - Science China Chemistry

JF - Science China Chemistry

IS - 8

ER -

Recent advances of mixed-transition-metal-substituted polyoxometalates

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this