Recent advances in metal-organic frameworks for lithium metal anode protection

Ying Du; Xing Gao; Siwu Li; Lu Wang; Bo Wang

doi:10.1016/j.cclet.2019.06.013

Recent advances in metal-organic frameworks for lithium metal anode protection

Ying Du, Xing Gao, Siwu Li, Lu Wang^*, Bo Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

43 Citations (Scopus)

Abstract

The lithium metal battery has been considered as a promising candidate for next generation batteries. However, safety concerns caused by uncontrollable lithium dendrite growth on lithium anode are severely hampering the commercial application. Metal-organic frameworks (MOFs) become one of the most attractive materials due to the high porosity, structural designability and tunability. With unique open channels and pores as well as functional components in MOFs, the transportation and deposition of lithium ions can be regulated, which leads to enhanced electrochemical properties. Various strategies for lithium metal protection are proposed in recent works on applications of MOFs in lithium metal batteries. In this review, we highlight latest key approaches in this field and discuss the prospects for MOFs in advanced Li anodes.

Original language	English
Pages (from-to)	609-616
Number of pages	8
Journal	Chinese Chemical Letters
Volume	31
Issue number	3
DOIs	https://doi.org/10.1016/j.cclet.2019.06.013
Publication status	Published - Mar 2020

Keywords

Li anode
Li dendrite
Lithium metal batteries
Metal-organic frameworks
Protection

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10.1016/j.cclet.2019.06.013

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title = "Recent advances in metal-organic frameworks for lithium metal anode protection",

abstract = "The lithium metal battery has been considered as a promising candidate for next generation batteries. However, safety concerns caused by uncontrollable lithium dendrite growth on lithium anode are severely hampering the commercial application. Metal-organic frameworks (MOFs) become one of the most attractive materials due to the high porosity, structural designability and tunability. With unique open channels and pores as well as functional components in MOFs, the transportation and deposition of lithium ions can be regulated, which leads to enhanced electrochemical properties. Various strategies for lithium metal protection are proposed in recent works on applications of MOFs in lithium metal batteries. In this review, we highlight latest key approaches in this field and discuss the prospects for MOFs in advanced Li anodes.",

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AU - Du, Ying

AU - Gao, Xing

AU - Li, Siwu

AU - Wang, Lu

AU - Wang, Bo

PY - 2020/3

Y1 - 2020/3

N2 - The lithium metal battery has been considered as a promising candidate for next generation batteries. However, safety concerns caused by uncontrollable lithium dendrite growth on lithium anode are severely hampering the commercial application. Metal-organic frameworks (MOFs) become one of the most attractive materials due to the high porosity, structural designability and tunability. With unique open channels and pores as well as functional components in MOFs, the transportation and deposition of lithium ions can be regulated, which leads to enhanced electrochemical properties. Various strategies for lithium metal protection are proposed in recent works on applications of MOFs in lithium metal batteries. In this review, we highlight latest key approaches in this field and discuss the prospects for MOFs in advanced Li anodes.

AB - The lithium metal battery has been considered as a promising candidate for next generation batteries. However, safety concerns caused by uncontrollable lithium dendrite growth on lithium anode are severely hampering the commercial application. Metal-organic frameworks (MOFs) become one of the most attractive materials due to the high porosity, structural designability and tunability. With unique open channels and pores as well as functional components in MOFs, the transportation and deposition of lithium ions can be regulated, which leads to enhanced electrochemical properties. Various strategies for lithium metal protection are proposed in recent works on applications of MOFs in lithium metal batteries. In this review, we highlight latest key approaches in this field and discuss the prospects for MOFs in advanced Li anodes.

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KW - Li dendrite

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KW - Protection

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Recent advances in metal-organic frameworks for lithium metal anode protection

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Keywords

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