Preparation and structure characterization of (AG)(DNP)

Xiao Jing Qiao; Ren Guang Yu; Tong Lai Zhang; Jian Guo Zhang; Kai Bei Yu

Preparation and structure characterization of (AG)(DNP)

Xiao Jing Qiao, Ren Guang Yu, Tong Lai Zhang, Jian Guo Zhang, Kai Bei Yu

School of Mechatronical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new ionic compound (AG)(DNP) was prepared by using amido (AG) carbamidine bicarbonate and 2, 4-dinitrophenol (DNP) as reagents. The characterization was carried out by means of single crystal X-ray diffraction analysis, elemental analysis and IR measurement. The crystal is in monoclinic system with space group P2₁/n. The unit cell parameters are as follows: a = 0.4922(1) nm, b = 2.3307(3) nm, c = 0.9404(6) nm, β = 91.621(12)°, Z = 2, D _c = 1.590 g/cm³, F(000) = 144. Amido (AG) cation and 2,4-dinitrophenol (DNP) anion are combined with electrostatic interactions and the molecule is combined with intermolecular hydrogen bonds. Its thermal performance was studied by TG-DTG and DSC techniques. The result shows that the title compound would be a very promising gas generating agent.

Original language	English
Pages (from-to)	1095-1098
Number of pages	4
Journal	Chinese Journal of Organic Chemistry
Volume	24
Issue number	9
Publication status	Published - Sept 2004

Keywords

2,4-dinitrophenol
Amido carbamidine
Crystal structure
Synthesis

Cite this

Qiao, X. J., Yu, R. G., Zhang, T. L., Zhang, J. G., & Yu, K. B. (2004). Preparation and structure characterization of (AG)(DNP). Chinese Journal of Organic Chemistry, 24(9), 1095-1098.

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title = "Preparation and structure characterization of (AG)(DNP)",

abstract = "A new ionic compound (AG)(DNP) was prepared by using amido (AG) carbamidine bicarbonate and 2, 4-dinitrophenol (DNP) as reagents. The characterization was carried out by means of single crystal X-ray diffraction analysis, elemental analysis and IR measurement. The crystal is in monoclinic system with space group P21/n. The unit cell parameters are as follows: a = 0.4922(1) nm, b = 2.3307(3) nm, c = 0.9404(6) nm, β = 91.621(12)°, Z = 2, D c = 1.590 g/cm3, F(000) = 144. Amido (AG) cation and 2,4-dinitrophenol (DNP) anion are combined with electrostatic interactions and the molecule is combined with intermolecular hydrogen bonds. Its thermal performance was studied by TG-DTG and DSC techniques. The result shows that the title compound would be a very promising gas generating agent.",

keywords = "2,4-dinitrophenol, Amido carbamidine, Crystal structure, Synthesis",

author = "Qiao, {Xiao Jing} and Yu, {Ren Guang} and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Yu, {Kai Bei}",

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language = "English",

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pages = "1095--1098",

journal = "Chinese Journal of Organic Chemistry",

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TY - JOUR

T1 - Preparation and structure characterization of (AG)(DNP)

AU - Qiao, Xiao Jing

AU - Yu, Ren Guang

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Yu, Kai Bei

PY - 2004/9

Y1 - 2004/9

N2 - A new ionic compound (AG)(DNP) was prepared by using amido (AG) carbamidine bicarbonate and 2, 4-dinitrophenol (DNP) as reagents. The characterization was carried out by means of single crystal X-ray diffraction analysis, elemental analysis and IR measurement. The crystal is in monoclinic system with space group P21/n. The unit cell parameters are as follows: a = 0.4922(1) nm, b = 2.3307(3) nm, c = 0.9404(6) nm, β = 91.621(12)°, Z = 2, D c = 1.590 g/cm3, F(000) = 144. Amido (AG) cation and 2,4-dinitrophenol (DNP) anion are combined with electrostatic interactions and the molecule is combined with intermolecular hydrogen bonds. Its thermal performance was studied by TG-DTG and DSC techniques. The result shows that the title compound would be a very promising gas generating agent.

AB - A new ionic compound (AG)(DNP) was prepared by using amido (AG) carbamidine bicarbonate and 2, 4-dinitrophenol (DNP) as reagents. The characterization was carried out by means of single crystal X-ray diffraction analysis, elemental analysis and IR measurement. The crystal is in monoclinic system with space group P21/n. The unit cell parameters are as follows: a = 0.4922(1) nm, b = 2.3307(3) nm, c = 0.9404(6) nm, β = 91.621(12)°, Z = 2, D c = 1.590 g/cm3, F(000) = 144. Amido (AG) cation and 2,4-dinitrophenol (DNP) anion are combined with electrostatic interactions and the molecule is combined with intermolecular hydrogen bonds. Its thermal performance was studied by TG-DTG and DSC techniques. The result shows that the title compound would be a very promising gas generating agent.

KW - 2,4-dinitrophenol

KW - Amido carbamidine

KW - Crystal structure

KW - Synthesis

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M3 - Article

AN - SCOPUS:5444219868

SN - 0253-2786

VL - 24

SP - 1095

EP - 1098

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 9

ER -

Preparation and structure characterization of (AG)(DNP)

Abstract

Keywords

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