Palladium-catalyzed C(sp3)-C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes

Guilong Cai; Yingda Huang; Tingting Du; Shaowen Zhang; Bo Yao; Xiaofang Li

doi:10.1039/c6cc01312k

Palladium-catalyzed C(sp³)-C(sp²) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes

Guilong Cai, Yingda Huang, Tingting Du, Shaowen Zhang, Bo Yao^*, Xiaofang Li

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The first C(sp³)-C(sp²) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.

Original language	English
Pages (from-to)	5425-5427
Number of pages	3
Journal	Chemical Communications
Volume	52
Issue number	31
DOIs	https://doi.org/10.1039/c6cc01312k
Publication status	Published - 21 Apr 2016

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10.1039/c6cc01312k

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title = "Palladium-catalyzed C(sp3)-C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes",

abstract = "The first C(sp3)-C(sp2) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.",

author = "Guilong Cai and Yingda Huang and Tingting Du and Shaowen Zhang and Bo Yao and Xiaofang Li",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

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language = "English",

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Palladium-catalyzed C(sp³)-C(sp²) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes. / Cai, Guilong; Huang, Yingda; Du, Tingting et al.
In: Chemical Communications, Vol. 52, No. 31, 21.04.2016, p. 5425-5427.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Palladium-catalyzed C(sp3)-C(sp2) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides

T2 - Efficient synthesis of functionalized benzyltrimethylsilanes

AU - Cai, Guilong

AU - Huang, Yingda

AU - Du, Tingting

AU - Zhang, Shaowen

AU - Yao, Bo

AU - Li, Xiaofang

PY - 2016/4/21

Y1 - 2016/4/21

N2 - The first C(sp3)-C(sp2) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.

AB - The first C(sp3)-C(sp2) cross-coupling of rare-earth metal alkyl complexes with aryl bromides has been developed. This reaction was conducted at low catalyst loading (0.5 mol%) and exhibited a broad substrate scope, thus providing a facile method for the synthesis of benzyltrimethylsilanes with diverse functional groups.

UR - http://www.scopus.com/inward/record.url?scp=84964502182&partnerID=8YFLogxK

U2 - 10.1039/c6cc01312k

DO - 10.1039/c6cc01312k

M3 - Article

AN - SCOPUS:84964502182

SN - 1359-7345

VL - 52

SP - 5425

EP - 5427

JO - Chemical Communications

JF - Chemical Communications

IS - 31

ER -

Palladium-catalyzed C(sp³)-C(sp²) cross-coupling of homoleptic rare-earth metal trialkyl complexes with aryl bromides: Efficient synthesis of functionalized benzyltrimethylsilanes

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