Organic aluminum hydrides catalyze nitrile hydroboration

Wenqing Liu; Yi Ding; Da Jin; Qiumiao Shen; Ben Yan; Xiaoli Ma; Zhi Yang

doi:10.1039/c9gc01659g

Organic aluminum hydrides catalyze nitrile hydroboration

Wenqing Liu, Yi Ding, Da Jin, Qiumiao Shen, Ben Yan, Xiaoli Ma^*, Zhi Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

60 Citations (Scopus)

Abstract

Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

Original language	English
Pages (from-to)	3812-3815
Number of pages	4
Journal	Green Chemistry
Volume	21
Issue number	14
DOIs	https://doi.org/10.1039/c9gc01659g
Publication status	Published - 2019

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title = "Organic aluminum hydrides catalyze nitrile hydroboration",

abstract = "Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.",

author = "Wenqing Liu and Yi Ding and Da Jin and Qiumiao Shen and Ben Yan and Xiaoli Ma and Zhi Yang",

note = "Publisher Copyright: {\textcopyright} 2019 The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c9gc01659g",

language = "English",

volume = "21",

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T1 - Organic aluminum hydrides catalyze nitrile hydroboration

AU - Liu, Wenqing

AU - Ding, Yi

AU - Jin, Da

AU - Shen, Qiumiao

AU - Yan, Ben

AU - Ma, Xiaoli

AU - Yang, Zhi

PY - 2019

Y1 - 2019

N2 - Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

AB - Economical and eco-friendly aluminum hydrides were shown to be highly efficient catalysts for the solvent-free hydroboration of various nitriles using pinacolborane. The catalytic activities of three organic aluminum hydrides were compared. Mechanism investigation experiments revealed that nitrile was reduced to an imine intermediate by aluminum hydrides.

UR - http://www.scopus.com/inward/record.url?scp=85069536379&partnerID=8YFLogxK

U2 - 10.1039/c9gc01659g

DO - 10.1039/c9gc01659g

M3 - Article

AN - SCOPUS:85069536379

SN - 1463-9262

VL - 21

SP - 3812

EP - 3815

JO - Green Chemistry

JF - Green Chemistry

IS - 14

ER -

Organic aluminum hydrides catalyze nitrile hydroboration

Abstract

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