One-dimensional arsenic-vanadium cluster chain bridged by two Co(en)2 groups

Wei Ming Bu; Guo Yu Yang; Ling Ye; Ji Qing Xu; Yu Guo Fan

doi:10.1246/cl.2000.462

One-dimensional arsenic-vanadium cluster chain bridged by two Co(en)₂ groups

Wei Ming Bu, Guo Yu Yang, Ling Ye, Ji Qing Xu, Yu Guo Fan^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

31 Citations (Scopus)

Abstract

The hydrothermal reaction of As₂O₃, V₂O₅, Co(Ac)₂, H₃PO₄, en and H₂O produces [Co^II(en)₃][{Co^II(en)₂}₂- As^III₆V^IV ₁₅O₄₂]·4H₂O, which consists of a one-dimensional arsenic-vanadium cluster chain bridged by two different geometries of Co(en)₂ groups. The interactions, which are established through hydrogen-bonding involving water molecules, the amine nitrogens, and terminal oxygen atoms, result in three-dimensional hydrogen-bonding network. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.

Original language	English
Pages (from-to)	462-463
Number of pages	2
Journal	Chemistry Letters
Issue number	5
DOIs	https://doi.org/10.1246/cl.2000.462
Publication status	Published - 2000
Externally published	Yes

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title = "One-dimensional arsenic-vanadium cluster chain bridged by two Co(en)2 groups",

abstract = "The hydrothermal reaction of As2O3, V2O5, Co(Ac)2, H3PO4, en and H2O produces [CoII(en)3][{CoII(en)2}2- AsIII6VIV 15O42]·4H2O, which consists of a one-dimensional arsenic-vanadium cluster chain bridged by two different geometries of Co(en)2 groups. The interactions, which are established through hydrogen-bonding involving water molecules, the amine nitrogens, and terminal oxygen atoms, result in three-dimensional hydrogen-bonding network. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.",

author = "Bu, {Wei Ming} and Yang, {Guo Yu} and Ling Ye and Xu, {Ji Qing} and Fan, {Yu Guo}",

year = "2000",

doi = "10.1246/cl.2000.462",

language = "English",

pages = "462--463",

journal = "Chemistry Letters",

issn = "0366-7022",

publisher = "The Chemical Society of Japan",

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T1 - One-dimensional arsenic-vanadium cluster chain bridged by two Co(en)2 groups

AU - Bu, Wei Ming

AU - Yang, Guo Yu

AU - Ye, Ling

AU - Xu, Ji Qing

AU - Fan, Yu Guo

PY - 2000

Y1 - 2000

N2 - The hydrothermal reaction of As2O3, V2O5, Co(Ac)2, H3PO4, en and H2O produces [CoII(en)3][{CoII(en)2}2- AsIII6VIV 15O42]·4H2O, which consists of a one-dimensional arsenic-vanadium cluster chain bridged by two different geometries of Co(en)2 groups. The interactions, which are established through hydrogen-bonding involving water molecules, the amine nitrogens, and terminal oxygen atoms, result in three-dimensional hydrogen-bonding network. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.

AB - The hydrothermal reaction of As2O3, V2O5, Co(Ac)2, H3PO4, en and H2O produces [CoII(en)3][{CoII(en)2}2- AsIII6VIV 15O42]·4H2O, which consists of a one-dimensional arsenic-vanadium cluster chain bridged by two different geometries of Co(en)2 groups. The interactions, which are established through hydrogen-bonding involving water molecules, the amine nitrogens, and terminal oxygen atoms, result in three-dimensional hydrogen-bonding network. Magnetic measurement indicates that the overall magnetic behavior is weakly antiferromagnetic.

UR - http://www.scopus.com/inward/record.url?scp=0034337727&partnerID=8YFLogxK

U2 - 10.1246/cl.2000.462

DO - 10.1246/cl.2000.462

M3 - Article

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SN - 0366-7022

SP - 462

EP - 463

JO - Chemistry Letters

JF - Chemistry Letters

IS - 5

ER -

One-dimensional arsenic-vanadium cluster chain bridged by two Co(en)₂ groups

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