(NH4)4Na2[Mo2 V21VV6VO28].10H 2O

Yan Xu; Ji Qing Xu; Guo Yu Yang; Yan Xing; Yong Hua Lin; Heng Qing Jia

doi:10.1107/S0108270198008853

(NH₄)₄Na₂[Mo₂ V₂^1VV₆^VO₂₈].10H ₂O

Yan Xu, Ji Qing Xu^*, Guo Yu Yang, Yan Xing, Yong Hua Lin, Heng Qing Jia

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

The title compound, tetraammonium disodium octacosaoxo(dimolybdenumoctavanadium)ate decahydrate, is a mixed V/Mo salt which has a well known decavanadate structure. The centrosymmetric polyanion consists of eight (V/Mo)O₆, and two VO₆ edge-sharing distorted octahedra. Each of the two Na⁺ cations is surrounded by six water molecules in a distorted octahedral arrangement. The V-O and (V/Mo)-O distances are between 1-571 (6) and 2.432 (5) Å.

Original language	English
Pages (from-to)	1733-1735
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	54
Issue number	12
DOIs	https://doi.org/10.1107/S0108270198008853
Publication status	Published - 15 Dec 1998
Externally published	Yes

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title = "(NH4)4Na2[Mo2 V21VV6VO28].10H 2O",

abstract = "The title compound, tetraammonium disodium octacosaoxo(dimolybdenumoctavanadium)ate decahydrate, is a mixed V/Mo salt which has a well known decavanadate structure. The centrosymmetric polyanion consists of eight (V/Mo)O6, and two VO6 edge-sharing distorted octahedra. Each of the two Na+ cations is surrounded by six water molecules in a distorted octahedral arrangement. The V-O and (V/Mo)-O distances are between 1-571 (6) and 2.432 (5) {\AA}.",

author = "Yan Xu and Xu, {Ji Qing} and Yang, {Guo Yu} and Yan Xing and Lin, {Yong Hua} and Jia, {Heng Qing}",

year = "1998",

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doi = "10.1107/S0108270198008853",

language = "English",

volume = "54",

pages = "1733--1735",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

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TY - JOUR

T1 - (NH4)4Na2[Mo2 V21VV6VO28].10H 2O

AU - Xu, Yan

AU - Xu, Ji Qing

AU - Yang, Guo Yu

AU - Xing, Yan

AU - Lin, Yong Hua

AU - Jia, Heng Qing

PY - 1998/12/15

Y1 - 1998/12/15

N2 - The title compound, tetraammonium disodium octacosaoxo(dimolybdenumoctavanadium)ate decahydrate, is a mixed V/Mo salt which has a well known decavanadate structure. The centrosymmetric polyanion consists of eight (V/Mo)O6, and two VO6 edge-sharing distorted octahedra. Each of the two Na+ cations is surrounded by six water molecules in a distorted octahedral arrangement. The V-O and (V/Mo)-O distances are between 1-571 (6) and 2.432 (5) Å.

AB - The title compound, tetraammonium disodium octacosaoxo(dimolybdenumoctavanadium)ate decahydrate, is a mixed V/Mo salt which has a well known decavanadate structure. The centrosymmetric polyanion consists of eight (V/Mo)O6, and two VO6 edge-sharing distorted octahedra. Each of the two Na+ cations is surrounded by six water molecules in a distorted octahedral arrangement. The V-O and (V/Mo)-O distances are between 1-571 (6) and 2.432 (5) Å.

UR - http://www.scopus.com/inward/record.url?scp=3242825768&partnerID=8YFLogxK

U2 - 10.1107/S0108270198008853

DO - 10.1107/S0108270198008853

M3 - Article

AN - SCOPUS:3242825768

SN - 0108-2701

VL - 54

SP - 1733

EP - 1735

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 12

ER -

(NH₄)₄Na₂[Mo₂ V₂^1VV₆^VO₂₈].10H ₂O

Abstract

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