Nanosized silica grafted hyperbranched poly (amine-ester) reinforced and toughened PVC

Hui Zhao; Yun Jun Luo; Jie Li; Min Xia

Nanosized silica grafted hyperbranched poly (amine-ester) reinforced and toughened PVC

Hui Zhao^*, Yun Jun Luo, Jie Li, Min Xia

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Silica was modified by KH-550 and hyperbranched poly (amine-ester) (HBP) and PVC/SiO₂ composite was prepared by melt-blending method. The structure and properties of the composites were characterized by means of SEM and mechanical properties tests etc.. The results show that addition of nano SiO₂ improves the mechanical properties of PVC, and the reinforcing and toughening effect are the best when the content of nano SiO₂ is 1%. The TEM photograph appears that nano SiO₂ modified with hyperbranched poly (amine-ester) are distributed in PVC more homogeneously, so the mechanical properties of PVC/SiO₂-HBP were the highest. Compared with PVC, the tensile strength, elongation at break, impact strength and flexural modulus of PVC/SiO₂-HBP composite is increased by 24.68%, 15.73%, 4.07% and 184.84% respectively. The processing properties of the composite are also improved efficiently.

Original language	English
Pages (from-to)	258-261
Number of pages	4
Journal	Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering
Volume	21
Issue number	5
Publication status	Published - Sept 2005

Keywords

Hyperbranched poly (amine-ester)
Mechanical properties
Nanosized-SiO
Process properties
Surface modification

Cite this

@article{b517655fee434b989fd1c50729ce677c,

title = "Nanosized silica grafted hyperbranched poly (amine-ester) reinforced and toughened PVC",

abstract = "Silica was modified by KH-550 and hyperbranched poly (amine-ester) (HBP) and PVC/SiO2 composite was prepared by melt-blending method. The structure and properties of the composites were characterized by means of SEM and mechanical properties tests etc.. The results show that addition of nano SiO2 improves the mechanical properties of PVC, and the reinforcing and toughening effect are the best when the content of nano SiO2 is 1%. The TEM photograph appears that nano SiO2 modified with hyperbranched poly (amine-ester) are distributed in PVC more homogeneously, so the mechanical properties of PVC/SiO2-HBP were the highest. Compared with PVC, the tensile strength, elongation at break, impact strength and flexural modulus of PVC/SiO2-HBP composite is increased by 24.68%, 15.73%, 4.07% and 184.84% respectively. The processing properties of the composite are also improved efficiently.",

keywords = "Hyperbranched poly (amine-ester), Mechanical properties, Nanosized-SiO, Process properties, Surface modification",

author = "Hui Zhao and Luo, {Yun Jun} and Jie Li and Min Xia",

year = "2005",

month = sep,

language = "English",

volume = "21",

pages = "258--261",

journal = "Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering",

issn = "1000-7555",

publisher = "Chengdu University of Science and Technology",

number = "5",

}

TY - JOUR

T1 - Nanosized silica grafted hyperbranched poly (amine-ester) reinforced and toughened PVC

AU - Zhao, Hui

AU - Luo, Yun Jun

AU - Li, Jie

AU - Xia, Min

PY - 2005/9

Y1 - 2005/9

N2 - Silica was modified by KH-550 and hyperbranched poly (amine-ester) (HBP) and PVC/SiO2 composite was prepared by melt-blending method. The structure and properties of the composites were characterized by means of SEM and mechanical properties tests etc.. The results show that addition of nano SiO2 improves the mechanical properties of PVC, and the reinforcing and toughening effect are the best when the content of nano SiO2 is 1%. The TEM photograph appears that nano SiO2 modified with hyperbranched poly (amine-ester) are distributed in PVC more homogeneously, so the mechanical properties of PVC/SiO2-HBP were the highest. Compared with PVC, the tensile strength, elongation at break, impact strength and flexural modulus of PVC/SiO2-HBP composite is increased by 24.68%, 15.73%, 4.07% and 184.84% respectively. The processing properties of the composite are also improved efficiently.

AB - Silica was modified by KH-550 and hyperbranched poly (amine-ester) (HBP) and PVC/SiO2 composite was prepared by melt-blending method. The structure and properties of the composites were characterized by means of SEM and mechanical properties tests etc.. The results show that addition of nano SiO2 improves the mechanical properties of PVC, and the reinforcing and toughening effect are the best when the content of nano SiO2 is 1%. The TEM photograph appears that nano SiO2 modified with hyperbranched poly (amine-ester) are distributed in PVC more homogeneously, so the mechanical properties of PVC/SiO2-HBP were the highest. Compared with PVC, the tensile strength, elongation at break, impact strength and flexural modulus of PVC/SiO2-HBP composite is increased by 24.68%, 15.73%, 4.07% and 184.84% respectively. The processing properties of the composite are also improved efficiently.

KW - Hyperbranched poly (amine-ester)

KW - Mechanical properties

KW - Nanosized-SiO

KW - Process properties

KW - Surface modification

UR - http://www.scopus.com/inward/record.url?scp=26944443426&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:26944443426

SN - 1000-7555

VL - 21

SP - 258

EP - 261

JO - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

JF - Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering

IS - 5

ER -

Nanosized silica grafted hyperbranched poly (amine-ester) reinforced and toughened PVC

Abstract

Keywords

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