MgnBu2 Catalyzed the Hydroalkoxylation of Carbodiimides

Luming Han; Ben Yan; Congjian Ni; Ziyuan Pang; Xiaoli Ma; Zhi Yang

doi:10.1002/slct.202304712

MgⁿBu₂ Catalyzed the Hydroalkoxylation of Carbodiimides

Luming Han, Ben Yan, Congjian Ni, Ziyuan Pang, Xiaoli Ma^*, Zhi Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The commercially available alkaline earth-metal compound MgⁿBu₂ can act as a highly efficient pre-catalyst under mild conditions for the catalytic addition of alcohols to carbodiimides. To the best of our knowledge, it has not been reported in alkaline earth-metal catalyzing reactions. A possible mechanistic pathway is proposed based on the stoichiometric experiments and the previously published literature.

Original language	English
Article number	e202304712
Journal	ChemistrySelect
Volume	9
Issue number	12
DOIs	https://doi.org/10.1002/slct.202304712
Publication status	Published - 26 Mar 2024

Keywords

Carbodiimide
Hydroalkoxylation
MgBu
and Isourea

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10.1002/slct.202304712

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title = "MgnBu2 Catalyzed the Hydroalkoxylation of Carbodiimides",

abstract = "The commercially available alkaline earth-metal compound MgnBu2 can act as a highly efficient pre-catalyst under mild conditions for the catalytic addition of alcohols to carbodiimides. To the best of our knowledge, it has not been reported in alkaline earth-metal catalyzing reactions. A possible mechanistic pathway is proposed based on the stoichiometric experiments and the previously published literature.",

keywords = "Carbodiimide, Hydroalkoxylation, MgBu, and Isourea",

author = "Luming Han and Ben Yan and Congjian Ni and Ziyuan Pang and Xiaoli Ma and Zhi Yang",

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T1 - MgnBu2 Catalyzed the Hydroalkoxylation of Carbodiimides

AU - Han, Luming

AU - Yan, Ben

AU - Ni, Congjian

AU - Pang, Ziyuan

AU - Ma, Xiaoli

AU - Yang, Zhi

PY - 2024/3/26

Y1 - 2024/3/26

N2 - The commercially available alkaline earth-metal compound MgnBu2 can act as a highly efficient pre-catalyst under mild conditions for the catalytic addition of alcohols to carbodiimides. To the best of our knowledge, it has not been reported in alkaline earth-metal catalyzing reactions. A possible mechanistic pathway is proposed based on the stoichiometric experiments and the previously published literature.

AB - The commercially available alkaline earth-metal compound MgnBu2 can act as a highly efficient pre-catalyst under mild conditions for the catalytic addition of alcohols to carbodiimides. To the best of our knowledge, it has not been reported in alkaline earth-metal catalyzing reactions. A possible mechanistic pathway is proposed based on the stoichiometric experiments and the previously published literature.

KW - Carbodiimide

KW - Hydroalkoxylation

KW - MgBu

KW - and Isourea

UR - http://www.scopus.com/inward/record.url?scp=85188170847&partnerID=8YFLogxK

U2 - 10.1002/slct.202304712

DO - 10.1002/slct.202304712

M3 - Article

AN - SCOPUS:85188170847

SN - 2365-6549

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JO - ChemistrySelect

JF - ChemistrySelect

IS - 12

M1 - e202304712

ER -

MgⁿBu₂ Catalyzed the Hydroalkoxylation of Carbodiimides

Abstract

Keywords

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