TY - JOUR
T1 - LiBa1.5[B5O8(OH)3]
T2 - A new 1-D metal borate chain constructed from B5O9(OH) 36 - Cluster units
AU - Wu, Han Qing
AU - Yang, Bai Fei
AU - He, Huan
AU - Yang, Guo Yu
PY - 2014
Y1 - 2014
N2 - A new mixed metal borate LiBa1.5[B5O 8(OH)3] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a = 11.2839(7) Å, b = 7.3974(4) Å, c = 20.7151(13) Å, β = 103.392(6), V = 1682.10(17) Å3 and Z = 8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B5O 9(OH)36 - cluster units. These BO chains are further linked by the Ba2 + and Li+ cations to form a 3-D framework.
AB - A new mixed metal borate LiBa1.5[B5O 8(OH)3] (1) has been hydrothermally synthesized and structurally characterized by FT-IR spectroscopy, powder X-ray diffraction, single crystal X-ray diffraction, and thermogravimetric analysis, respectively. 1 crystallizes in the monoclinic system, space group C2/c, a = 11.2839(7) Å, b = 7.3974(4) Å, c = 20.7151(13) Å, β = 103.392(6), V = 1682.10(17) Å3 and Z = 8. The structure consists of infinite one-dimensional (1-D) borate chains constructed from B5O 9(OH)36 - cluster units. These BO chains are further linked by the Ba2 + and Li+ cations to form a 3-D framework.
KW - Cluster
KW - Crystal structure
KW - Hydrothermal synthesis
KW - Metal borate
UR - http://www.scopus.com/inward/record.url?scp=84887597243&partnerID=8YFLogxK
U2 - 10.1016/j.inoche.2013.10.043
DO - 10.1016/j.inoche.2013.10.043
M3 - Article
AN - SCOPUS:84887597243
SN - 1387-7003
VL - 39
SP - 10
EP - 13
JO - Inorganic Chemistry Communications
JF - Inorganic Chemistry Communications
ER -