Li                         2                         Na                         2                         [B                         12                         O                         19                         (OH)                         2                         ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

Bei Bei Han; Jian Wen Cheng; Guo Yu Yang

doi:10.1039/c8ce02175a

Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

Bei Bei Han, Jian Wen Cheng^*, Guo Yu Yang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

7 Citations (Scopus)

Abstract

The solvothermal reaction of H ₃ BO ₃ , Li ₂ B ₄ O ₇ , Na ₂ B ₄ O ₇ ·10H ₂ O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B ₁₂ O ₂₂ (OH) ₂ ] ¹⁰⁻ cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.

Original language	English
Pages (from-to)	1262-1266
Number of pages	5
Journal	CrystEngComm
Volume	21
Issue number	8
DOIs	https://doi.org/10.1039/c8ce02175a
Publication status	Published - 2019

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Han, B. B., Cheng, J. W., & Yang, G. Y. (2019). Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. CrystEngComm, 21(8), 1262-1266. https://doi.org/10.1039/c8ce02175a

Han, Bei Bei ; Cheng, Jian Wen ; Yang, Guo Yu. / Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ] : a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. In: CrystEngComm. 2019 ; Vol. 21, No. 8. pp. 1262-1266.

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title = "Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units",

abstract = " The solvothermal reaction of H 3 BO 3 , Li 2 B 4 O 7 , Na 2 B 4 O 7 ·10H 2 O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li 2 Na 2 [B 12 O 19 (OH) 2 ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B 12 O 22 (OH) 2 ] 10− cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.",

author = "Han, {Bei Bei} and Cheng, {Jian Wen} and Yang, {Guo Yu}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

doi = "10.1039/c8ce02175a",

language = "English",

volume = "21",

pages = "1262--1266",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

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}

Han, BB, Cheng, JW & Yang, GY 2019, 'Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units', CrystEngComm, vol. 21, no. 8, pp. 1262-1266. https://doi.org/10.1039/c8ce02175a

Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. / Han, Bei Bei; Cheng, Jian Wen; Yang, Guo Yu.
In: CrystEngComm, Vol. 21, No. 8, 2019, p. 1262-1266.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Li 2 Na 2 [B 12 O 19 (OH) 2 ]

T2 - a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

AU - Han, Bei Bei

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2019

Y1 - 2019

N2 - The solvothermal reaction of H 3 BO 3 , Li 2 B 4 O 7 , Na 2 B 4 O 7 ·10H 2 O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li 2 Na 2 [B 12 O 19 (OH) 2 ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B 12 O 22 (OH) 2 ] 10− cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.

AB - The solvothermal reaction of H 3 BO 3 , Li 2 B 4 O 7 , Na 2 B 4 O 7 ·10H 2 O, 1,2-diaminopropane and pyridine led to a new open framework borate, Li 2 Na 2 [B 12 O 19 (OH) 2 ] (1). Compound 1 crystallizes in the monoclinic space group C2/c. Its structure contains a large cyclic [B 12 O 22 (OH) 2 ] 10− cluster, which is connected to six neighboring ones via corner-sharing O atoms to give a 6-connected pcu network via B-O-B bonds. Notably, large shuttle-like pores are observed along the [001] direction as well as 8-ring channels along the [101] direction, leading to an intersecting channel system. UV/vis diffuse reflectance analysis indicates that the compound has a wide transparency range with a short-wavelength absorption edge below 200 nm.

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U2 - 10.1039/c8ce02175a

DO - 10.1039/c8ce02175a

M3 - Article

AN - SCOPUS:85061788651

SN - 1466-8033

VL - 21

SP - 1262

EP - 1266

JO - CrystEngComm

JF - CrystEngComm

IS - 8

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Han BB, Cheng JW, Yang GY. Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units. CrystEngComm. 2019;21(8):1262-1266. doi: 10.1039/c8ce02175a

Li ₂ Na ₂ [B ₁₂ O ₁₉ (OH) ₂ ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units

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