Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

Zhi En Lin; You Wei Yao; Jie Zhang; Guo Yu Yang

doi:10.1039/b304778d

Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

Zhi En Lin, You Wei Yao, Jie Zhang, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Two hybrid zinc phosphates, [Zn(phen)]₂(H_1.5 PO₄)₂(H₂PO₄) (1) and [Zn(phen)]₂(HPO₄)(H₂PO₄)₂ ·xH₂O (x ≈ 0.5) (2), have been synthesized under hydrothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. They are the first members in the zinc-phosphate-phen system. The structure of 1 consists of two ZnO₃N₂ trigonal bipyramids bridged by three P-centered tetrahedra. 1 is novel in the sense that it provides the first example of a monomeric zinc phosphate crystallized in a non-centrosynmmetric space group. The one-dimensional structure of 2 consists of a network of strictly alternating ZnO₃N₂ trigonal bipyramids, HPO₄ and H₂PO₄ tetrahedra by sharing vertices. Interestingly, the chain-like structure of 2 can be generated from 1 by a shifting of Zn-O-P bonds.

Original language	English
Pages (from-to)	3160-3164
Number of pages	5
Journal	Dalton Transactions
Issue number	16
DOIs	https://doi.org/10.1039/b304778d
Publication status	Published - 21 Aug 2003
Externally published	Yes

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title = "Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative",

abstract = "Two hybrid zinc phosphates, [Zn(phen)]2(H1.5 PO4)2(H2PO4) (1) and [Zn(phen)]2(HPO4)(H2PO4)2 ·xH2O (x ≈ 0.5) (2), have been synthesized under hydrothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. They are the first members in the zinc-phosphate-phen system. The structure of 1 consists of two ZnO3N2 trigonal bipyramids bridged by three P-centered tetrahedra. 1 is novel in the sense that it provides the first example of a monomeric zinc phosphate crystallized in a non-centrosynmmetric space group. The one-dimensional structure of 2 consists of a network of strictly alternating ZnO3N2 trigonal bipyramids, HPO4 and H2PO4 tetrahedra by sharing vertices. Interestingly, the chain-like structure of 2 can be generated from 1 by a shifting of Zn-O-P bonds.",

author = "Lin, {Zhi En} and Yao, {You Wei} and Jie Zhang and Yang, {Guo Yu}",

year = "2003",

month = aug,

day = "21",

doi = "10.1039/b304778d",

language = "English",

pages = "3160--3164",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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T1 - Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

AU - Lin, Zhi En

AU - Yao, You Wei

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2003/8/21

Y1 - 2003/8/21

N2 - Two hybrid zinc phosphates, [Zn(phen)]2(H1.5 PO4)2(H2PO4) (1) and [Zn(phen)]2(HPO4)(H2PO4)2 ·xH2O (x ≈ 0.5) (2), have been synthesized under hydrothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. They are the first members in the zinc-phosphate-phen system. The structure of 1 consists of two ZnO3N2 trigonal bipyramids bridged by three P-centered tetrahedra. 1 is novel in the sense that it provides the first example of a monomeric zinc phosphate crystallized in a non-centrosynmmetric space group. The one-dimensional structure of 2 consists of a network of strictly alternating ZnO3N2 trigonal bipyramids, HPO4 and H2PO4 tetrahedra by sharing vertices. Interestingly, the chain-like structure of 2 can be generated from 1 by a shifting of Zn-O-P bonds.

AB - Two hybrid zinc phosphates, [Zn(phen)]2(H1.5 PO4)2(H2PO4) (1) and [Zn(phen)]2(HPO4)(H2PO4)2 ·xH2O (x ≈ 0.5) (2), have been synthesized under hydrothermal conditions in the presence of 1,10-phenanthroline (phen) ligands. They are the first members in the zinc-phosphate-phen system. The structure of 1 consists of two ZnO3N2 trigonal bipyramids bridged by three P-centered tetrahedra. 1 is novel in the sense that it provides the first example of a monomeric zinc phosphate crystallized in a non-centrosynmmetric space group. The one-dimensional structure of 2 consists of a network of strictly alternating ZnO3N2 trigonal bipyramids, HPO4 and H2PO4 tetrahedra by sharing vertices. Interestingly, the chain-like structure of 2 can be generated from 1 by a shifting of Zn-O-P bonds.

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DO - 10.1039/b304778d

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 16

ER -

Isolation of a monomeric hybrid zinc phosphate and its one-dimensional relative

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