Hydrothermal synthesis of one-dimensional molybdenum-vanadium cluster chain: [Ni(enMe)2]2-[Ni(enMe)2{HMo VI4MoV4VIV 8O40(VVO4)}]·4H2O

Xiao Bing Cui; Shou Tian Zheng; Guo Yu Yang

Hydrothermal synthesis of one-dimensional molybdenum-vanadium cluster chain: [Ni(enMe)₂]₂-[Ni(enMe)₂{HMo ^VI₄Mo^V₄V^IV ₈O₄₀(V^VO₄)}]·4H₂O

Xiao Bing Cui^*, Shou Tian Zheng, Guo Yu Yang

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

The novel polyoxometalate, [Ni(enMe)₂]₂[Ni(enMe) ₂{HMo^VI₄Mo^V₄V ^IV₈O₄₀(V^VO₄)}] ·4H₂O, was synthesized and characterized by elementary analysis, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group C2/c with a = 26.3006(6), b = 13.6195(3), c = 19.7122(5) Å, β = 105.8330(10)°, V = 6793.0(3) Å³, Z = 4, D_c = 2.566 g/cm³, M_r = 2623.96, μ = 3.507 mm^-1, F(000) = 5088, R = 0.0699, wR = 0.1526 and S = 1.018. The compound consists of infinite chains of [Ni(enMe)₂] ₂[Ni(enMe)₂{HMo^VI₄Mo ^V₄V^IV₈O₄₀(V ^VO₄)}]·4H₂O clusters covalently linked through [Ni(enMe)₂] group and another isolated [Ni(enMe) ₂]²⁺ cations, occupying the interchain regions and providing charge compensation.

Original language	English
Pages (from-to)	300-305
Number of pages	6
Journal	Jiegou Huaxue
Volume	23
Issue number	3
Publication status	Published - 2004
Externally published	Yes

Keywords

Crystal structure
Molybdenum
Polyoxometalate
Tetra-capped Keggin structure
Vanadium

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@article{1a6ca59aa8c24eb0badad636621375fd,

title = "Hydrothermal synthesis of one-dimensional molybdenum-vanadium cluster chain: [Ni(enMe)2]2-[Ni(enMe)2{HMo VI4MoV4VIV 8O40(VVO4)}]·4H2O",

abstract = "The novel polyoxometalate, [Ni(enMe)2]2[Ni(enMe) 2{HMoVI4MoV4V IV8O40(VVO4)}] ·4H2O, was synthesized and characterized by elementary analysis, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group C2/c with a = 26.3006(6), b = 13.6195(3), c = 19.7122(5) {\AA}, β = 105.8330(10)°, V = 6793.0(3) {\AA}3, Z = 4, Dc = 2.566 g/cm3, Mr = 2623.96, μ = 3.507 mm-1, F(000) = 5088, R = 0.0699, wR = 0.1526 and S = 1.018. The compound consists of infinite chains of [Ni(enMe)2] 2[Ni(enMe)2{HMoVI4Mo V4VIV8O40(V VO4)}]·4H2O clusters covalently linked through [Ni(enMe)2] group and another isolated [Ni(enMe) 2]2+ cations, occupying the interchain regions and providing charge compensation.",

keywords = "Crystal structure, Molybdenum, Polyoxometalate, Tetra-capped Keggin structure, Vanadium",

author = "Cui, {Xiao Bing} and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

language = "English",

volume = "23",

pages = "300--305",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "3",

}

TY - JOUR

T1 - Hydrothermal synthesis of one-dimensional molybdenum-vanadium cluster chain

T2 - [Ni(enMe)2]2-[Ni(enMe)2{HMo VI4MoV4VIV 8O40(VVO4)}]·4H2O

AU - Cui, Xiao Bing

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004

Y1 - 2004

N2 - The novel polyoxometalate, [Ni(enMe)2]2[Ni(enMe) 2{HMoVI4MoV4V IV8O40(VVO4)}] ·4H2O, was synthesized and characterized by elementary analysis, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group C2/c with a = 26.3006(6), b = 13.6195(3), c = 19.7122(5) Å, β = 105.8330(10)°, V = 6793.0(3) Å3, Z = 4, Dc = 2.566 g/cm3, Mr = 2623.96, μ = 3.507 mm-1, F(000) = 5088, R = 0.0699, wR = 0.1526 and S = 1.018. The compound consists of infinite chains of [Ni(enMe)2] 2[Ni(enMe)2{HMoVI4Mo V4VIV8O40(V VO4)}]·4H2O clusters covalently linked through [Ni(enMe)2] group and another isolated [Ni(enMe) 2]2+ cations, occupying the interchain regions and providing charge compensation.

AB - The novel polyoxometalate, [Ni(enMe)2]2[Ni(enMe) 2{HMoVI4MoV4V IV8O40(VVO4)}] ·4H2O, was synthesized and characterized by elementary analysis, IR spectra and X-ray diffraction. The compound crystallizes in monoclinic, space group C2/c with a = 26.3006(6), b = 13.6195(3), c = 19.7122(5) Å, β = 105.8330(10)°, V = 6793.0(3) Å3, Z = 4, Dc = 2.566 g/cm3, Mr = 2623.96, μ = 3.507 mm-1, F(000) = 5088, R = 0.0699, wR = 0.1526 and S = 1.018. The compound consists of infinite chains of [Ni(enMe)2] 2[Ni(enMe)2{HMoVI4Mo V4VIV8O40(V VO4)}]·4H2O clusters covalently linked through [Ni(enMe)2] group and another isolated [Ni(enMe) 2]2+ cations, occupying the interchain regions and providing charge compensation.

KW - Crystal structure

KW - Molybdenum

KW - Polyoxometalate

KW - Tetra-capped Keggin structure

KW - Vanadium

UR - http://www.scopus.com/inward/record.url?scp=4644305688&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:4644305688

SN - 0254-5861

VL - 23

SP - 300

EP - 305

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 3

ER -

Hydrothermal synthesis of one-dimensional molybdenum-vanadium cluster chain: [Ni(enMe)₂]₂-[Ni(enMe)₂{HMo ^VI₄Mo^V₄V^IV ₈O₄₀(V^VO₄)}]·4H₂O

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