Hydrothermal synthesis of lanthanide and lanthanide-transition-metal cluster organic frameworks via synergistic coordination strategy

Jian Wen Cheng, Guo Yu Yang*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

7 Citations (Scopus)

Abstract

The study of polynuclear lanthanide (Ln) complexes has been a field of rapid growth in coordination chemistry. Lanthanide clusters synthesized via a ligand-controlled hydrolytic approach using different flexible α-amino acids have been well summarized. In this chapter, we describe efforts to synthesize lanthanide and lanthanide-transition-metal (Ln-TM) cluster organic frameworks using rigid ligands of isonicotinic acid (HIN), 4-pyridin-4-ylbenzoic acid (HL), nicotinic acid (HNA), and 4-(3-pyridyl)benzoic acid (HL’) under hydrothermal condition. In addition, the synergistic coordination between these rigid ligands with other organic/inorganic ligands has also been discussed.

Original languageEnglish
Title of host publicationStructure and Bonding
PublisherSpringer Verlag
Pages97-120
Number of pages24
DOIs
Publication statusPublished - 1 Jan 2017
Externally publishedYes

Publication series

NameStructure and Bonding
Volume173
ISSN (Print)0081-5993
ISSN (Electronic)1616-8550

Keywords

  • Heterometallic compounds
  • Hydrothermal synthesis
  • Lanthanide cluster organic framework
  • Rigid ligands
  • Synergistic coordination

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