Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O

Lirong Zhang; Zhan Shi; Guoyu Yang; Xiaoming Chen; Shouhua Feng

doi:10.1006/jssc.1999.8478

Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)₂]₆[(VO)₁₂O₆B ₁₈O₃₉(OH)₃] · 13H₂O

Lirong Zhang, Zhan Shi, Guoyu Yang, Xiaoming Chen, Shouhua Feng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

51 Citations (Scopus)

Abstract

A hydrothermal reaction of NaVO₃, H₃BO₃, Zn(CH₃COO)₂, ethylenediamine, and H₂O gives a coordination cluster [Zn(en)₂]₆[(VO)₁₂O₆B ₁₈O₃₉(OH)₃] · 13H₂O (denoted on Zn₆V₁₂B₁₈). The Zn₆V₁₂B₁₈ crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) Å, c = 20.915(4) Å, V = 7751(2) Å³, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B₁₈O₃₉(OH)₃ sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V₆O₁₅ by six B-(μ₃-O)-V₂ bonds and three B₂-(μ₃-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B₁₈O₃₉(OH)₃ ring by one Zn-(μ₃-O)-B bond. A water molecule occupied the center of the Zn₆V₁₂B₁₈ cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.

Original language	English
Pages (from-to)	450-454
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	148
Issue number	2
DOIs	https://doi.org/10.1006/jssc.1999.8478
Publication status	Published - Dec 1999
Externally published	Yes

Keywords

Borate compound
Crystal structure
Hydrothermal synthesis
Polyoxovanadium
Transition metal complex

Access to Document

10.1006/jssc.1999.8478

Cite this

@article{9e1f4028c0144112868e058acbd52584,

title = "Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O",

abstract = "A hydrothermal reaction of NaVO3, H3BO3, Zn(CH3COO)2, ethylenediamine, and H2O gives a coordination cluster [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O (denoted on Zn6V12B18). The Zn6V12B18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) {\AA}, c = 20.915(4) {\AA}, V = 7751(2) {\AA}3, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B18O39(OH)3 sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V6O15 by six B-(μ3-O)-V2 bonds and three B2-(μ3-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B18O39(OH)3 ring by one Zn-(μ3-O)-B bond. A water molecule occupied the center of the Zn6V12B18 cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.",

keywords = "Borate compound, Crystal structure, Hydrothermal synthesis, Polyoxovanadium, Transition metal complex",

author = "Lirong Zhang and Zhan Shi and Guoyu Yang and Xiaoming Chen and Shouhua Feng",

year = "1999",

month = dec,

doi = "10.1006/jssc.1999.8478",

language = "English",

volume = "148",

pages = "450--454",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

}

TY - JOUR

T1 - Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O

AU - Zhang, Lirong

AU - Shi, Zhan

AU - Yang, Guoyu

AU - Chen, Xiaoming

AU - Feng, Shouhua

PY - 1999/12

Y1 - 1999/12

N2 - A hydrothermal reaction of NaVO3, H3BO3, Zn(CH3COO)2, ethylenediamine, and H2O gives a coordination cluster [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O (denoted on Zn6V12B18). The Zn6V12B18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) Å, c = 20.915(4) Å, V = 7751(2) Å3, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B18O39(OH)3 sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V6O15 by six B-(μ3-O)-V2 bonds and three B2-(μ3-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B18O39(OH)3 ring by one Zn-(μ3-O)-B bond. A water molecule occupied the center of the Zn6V12B18 cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.

AB - A hydrothermal reaction of NaVO3, H3BO3, Zn(CH3COO)2, ethylenediamine, and H2O gives a coordination cluster [Zn(en)2]6[(VO)12O6B 18O39(OH)3] · 13H2O (denoted on Zn6V12B18). The Zn6V12B18 crystallizes in a rhombohedral system with space group R-3 and unit cell parameters a = 20.686(3) Å, c = 20.915(4) Å, V = 7751(2) Å3, Z = 3, and R = 0.0689. The structure consists of an 18-membered ring of B18O39(OH)3 sand-wiched between two alternating edge-sharing vanadium-oxygen clusters V6O15 by six B-(μ3-O)-V2 bonds and three B2-(μ3-O)-V bonds. Each of the six zinc atoms coordinated with two ethylenediamine molecules and connected with the B18O39(OH)3 ring by one Zn-(μ3-O)-B bond. A water molecule occupied the center of the Zn6V12B18 cluster. The oxidation states of vanadium in the compound are V(IV) and V(V) in a ratio of 3:1. Other characterizations by IR spectroscopy, TGA, and DTA are also described.

KW - Borate compound

KW - Crystal structure

KW - Hydrothermal synthesis

KW - Polyoxovanadium

KW - Transition metal complex

UR - http://www.scopus.com/inward/record.url?scp=0001482331&partnerID=8YFLogxK

U2 - 10.1006/jssc.1999.8478

DO - 10.1006/jssc.1999.8478

M3 - Article

AN - SCOPUS:0001482331

SN - 0022-4596

VL - 148

SP - 450

EP - 454

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

Hydrothermal Synthesis and X-Ray Single Crystal Structure of [Zn(en)₂]₆[(VO)₁₂O₆B ₁₈O₃₉(OH)₃] · 13H₂O

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this