Hydrothermal synthesis and structure of a novel hybrid germanium vanadate: (2,2′-bpy)2(VVO2) 2(H2GeO4)·6H2O

Shou Tian Zheng; Jie Zhang; Guo Yu Yang

doi:10.1016/j.inoche.2004.05.007

Hydrothermal synthesis and structure of a novel hybrid germanium vanadate: (2,2^′-bpy)₂(V^VO₂) ₂(H₂GeO₄)·6H₂O

Shou Tian Zheng, Jie Zhang, Guo Yu Yang^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

A new hybrid germanium vanadate (2,2^′-bpy) ₂(V^VO₂)₂(H₂GeO ₄)·6H₂O 1 (2,2^′-bpy=2,2 ^′-bipyridine) was synthesized by hydrothermal method and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), IR, XRD and elemental analyses. Crystal data for 1: monoclinic, C2/c, a=16.6937(9) Å, b=11.3501(6) Å, c=17.4774(9) Å, β=118.19(2)°, V=2918.7(3) Å³, Z=4. Compound 1 is composed of the first germanium vanadate skeleton covalently attached to 2,2^′-bpy ligands.

Original language	English
Pages (from-to)	861-863
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	7
DOIs	https://doi.org/10.1016/j.inoche.2004.05.007
Publication status	Published - Jul 2004
Externally published	Yes

Keywords

Crystal structure
Germanate
Hydrothermal synthesis
Inorganic-organic hybrid
Vanadate

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10.1016/j.inoche.2004.05.007

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@article{9fddd0dd3196433785f2f67f6a3516af,

title = "Hydrothermal synthesis and structure of a novel hybrid germanium vanadate: (2,2′-bpy)2(VVO2) 2(H2GeO4)·6H2O",

abstract = "A new hybrid germanium vanadate (2,2′-bpy) 2(VVO2)2(H2GeO 4)·6H2O 1 (2,2′-bpy=2,2 ′-bipyridine) was synthesized by hydrothermal method and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), IR, XRD and elemental analyses. Crystal data for 1: monoclinic, C2/c, a=16.6937(9) {\AA}, b=11.3501(6) {\AA}, c=17.4774(9) {\AA}, β=118.19(2)°, V=2918.7(3) {\AA}3, Z=4. Compound 1 is composed of the first germanium vanadate skeleton covalently attached to 2,2′-bpy ligands.",

keywords = "Crystal structure, Germanate, Hydrothermal synthesis, Inorganic-organic hybrid, Vanadate",

author = "Zheng, {Shou Tian} and Jie Zhang and Yang, {Guo Yu}",

year = "2004",

month = jul,

doi = "10.1016/j.inoche.2004.05.007",

language = "English",

volume = "7",

pages = "861--863",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

number = "7",

}

TY - JOUR

T1 - Hydrothermal synthesis and structure of a novel hybrid germanium vanadate

T2 - (2,2′-bpy)2(VVO2) 2(H2GeO4)·6H2O

AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Yang, Guo Yu

PY - 2004/7

Y1 - 2004/7

N2 - A new hybrid germanium vanadate (2,2′-bpy) 2(VVO2)2(H2GeO 4)·6H2O 1 (2,2′-bpy=2,2 ′-bipyridine) was synthesized by hydrothermal method and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), IR, XRD and elemental analyses. Crystal data for 1: monoclinic, C2/c, a=16.6937(9) Å, b=11.3501(6) Å, c=17.4774(9) Å, β=118.19(2)°, V=2918.7(3) Å3, Z=4. Compound 1 is composed of the first germanium vanadate skeleton covalently attached to 2,2′-bpy ligands.

AB - A new hybrid germanium vanadate (2,2′-bpy) 2(VVO2)2(H2GeO 4)·6H2O 1 (2,2′-bpy=2,2 ′-bipyridine) was synthesized by hydrothermal method and structurally characterized by single-crystal X-ray diffraction, thermogravimetric analysis (TGA), IR, XRD and elemental analyses. Crystal data for 1: monoclinic, C2/c, a=16.6937(9) Å, b=11.3501(6) Å, c=17.4774(9) Å, β=118.19(2)°, V=2918.7(3) Å3, Z=4. Compound 1 is composed of the first germanium vanadate skeleton covalently attached to 2,2′-bpy ligands.

KW - Crystal structure

KW - Germanate

KW - Hydrothermal synthesis

KW - Inorganic-organic hybrid

KW - Vanadate

UR - http://www.scopus.com/inward/record.url?scp=3242738548&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2004.05.007

DO - 10.1016/j.inoche.2004.05.007

M3 - Article

AN - SCOPUS:3242738548

SN - 1387-7003

VL - 7

SP - 861

EP - 863

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 7

ER -

Hydrothermal synthesis and structure of a novel hybrid germanium vanadate: (2,2^′-bpy)₂(V^VO₂) ₂(H₂GeO₄)·6H₂O

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Keywords

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