Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex: Cd[C3N2H11]2[V8O 20]

Lirong Zhang; Zhan Shi; Guoyu Yang; Xiaoming Chen; Shouhua Feng

doi:10.1039/a908773g

Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex: Cd[C₃N₂H₁₁]₂[V₈O ₂₀]

Lirong Zhang, Zhan Shi, Guoyu Yang, Xiaoming Chen, Shouhua Feng^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

104 Citations (Scopus)

Abstract

The compound Cd[C₃N₂H₁₁]₂[V₈O ₂₀] was synthesized from the hydrothermal reactions of V₂O₅, CdSO₄, 1,2-diaminopropane (enMe) and water in the molar ratio 1:1:2.2:223. Its structure has been determined by single-crystal X-ray diffraction. This compound has an open three-dimensional framework structure consisting of [V₈O₂₀]^4- layers, composed of equal numbers of VO₄ tetrahedra and VO₅ pyramids connected by both corner and edge sharing. The Cd[enMeH]₂⁴⁺ complex occupies the interlayer space and connects with the vanadium oxide layers through four Cd-O bonds. This arrangement gives one-dimensional channels with 10-membered rings along the c axis.

Original language	English
Pages (from-to)	275-278
Number of pages	4
Journal	Journal of the Chemical Society. Dalton Transactions
Issue number	3
DOIs	https://doi.org/10.1039/a908773g
Publication status	Published - 2000
Externally published	Yes

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title = "Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex: Cd[C3N2H11]2[V8O 20]",

abstract = "The compound Cd[C3N2H11]2[V8O 20] was synthesized from the hydrothermal reactions of V2O5, CdSO4, 1,2-diaminopropane (enMe) and water in the molar ratio 1:1:2.2:223. Its structure has been determined by single-crystal X-ray diffraction. This compound has an open three-dimensional framework structure consisting of [V8O20]4- layers, composed of equal numbers of VO4 tetrahedra and VO5 pyramids connected by both corner and edge sharing. The Cd[enMeH]24+ complex occupies the interlayer space and connects with the vanadium oxide layers through four Cd-O bonds. This arrangement gives one-dimensional channels with 10-membered rings along the c axis.",

author = "Lirong Zhang and Zhan Shi and Guoyu Yang and Xiaoming Chen and Shouhua Feng",

year = "2000",

doi = "10.1039/a908773g",

language = "English",

pages = "275--278",

journal = "Journal of the Chemical Society. Dalton Transactions",

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publisher = "Royal Society of Chemistry",

number = "3",

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T1 - Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex

T2 - Cd[C3N2H11]2[V8O 20]

AU - Zhang, Lirong

AU - Shi, Zhan

AU - Yang, Guoyu

AU - Chen, Xiaoming

AU - Feng, Shouhua

PY - 2000

Y1 - 2000

N2 - The compound Cd[C3N2H11]2[V8O 20] was synthesized from the hydrothermal reactions of V2O5, CdSO4, 1,2-diaminopropane (enMe) and water in the molar ratio 1:1:2.2:223. Its structure has been determined by single-crystal X-ray diffraction. This compound has an open three-dimensional framework structure consisting of [V8O20]4- layers, composed of equal numbers of VO4 tetrahedra and VO5 pyramids connected by both corner and edge sharing. The Cd[enMeH]24+ complex occupies the interlayer space and connects with the vanadium oxide layers through four Cd-O bonds. This arrangement gives one-dimensional channels with 10-membered rings along the c axis.

AB - The compound Cd[C3N2H11]2[V8O 20] was synthesized from the hydrothermal reactions of V2O5, CdSO4, 1,2-diaminopropane (enMe) and water in the molar ratio 1:1:2.2:223. Its structure has been determined by single-crystal X-ray diffraction. This compound has an open three-dimensional framework structure consisting of [V8O20]4- layers, composed of equal numbers of VO4 tetrahedra and VO5 pyramids connected by both corner and edge sharing. The Cd[enMeH]24+ complex occupies the interlayer space and connects with the vanadium oxide layers through four Cd-O bonds. This arrangement gives one-dimensional channels with 10-membered rings along the c axis.

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DO - 10.1039/a908773g

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Hydrothermal synthesis and crystal structure of a layered vanadium oxide with an interlayer metal co-ordination complex: Cd[C₃N₂H₁₁]₂[V₈O ₂₀]

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