Hydrothermal synthesis and characterization of [Ni(phen)3]2[Mo8O26]·2H2O

R. Z. Wang; J. Q. Xu; G. Y. Yang; Y. F. Li; Y. H. Xing; D. M. Li; S. Q. Liu; W. M. Bu; L. Ye; Y. G. Fan

doi:10.1016/S1293-2558(00)01076-1

Hydrothermal synthesis and characterization of [Ni(phen)₃]₂[Mo₈O₂₆]·2H₂O

R. Z. Wang^*, J. Q. Xu, G. Y. Yang, Y. F. Li, Y. H. Xing, D. M. Li, S. Q. Liu, W. M. Bu, L. Ye, Y. G. Fan

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The reaction of MoO₃, H₂MoO₄ and Ni(Ac)₂·6H₂O with 1,10-phenanthroline by a hydrothermal method furnishes the discrete cluster [Ni(phen)₃]₂[Mo₈O₂₆]·2H₂O (1). The structure of 1 is triclinic, space group (Pl̄), a = 11.4965(10), b = 11.6829(13), c = 15.1518(15) Å α = 83.032(8), β = 71.557(7), γ = 78.319(7)°, R = 0.0433 for 7397 observed [I > 2<σ(I)] reflections. The crystallographically determined solid state structure of 1 shows that the cluster consists of two complex cations, one cluster anion [Mo₈O₂₆]^4- and two water molecules of crystallization. Each nickel ion is coordinated by six nitrogen atoms from three phenanthroline ligands, forming a distorted octahedron, and the anion has a β-configuration formed by eight edge-sharing MoO₆ octahedra. Compound 1 was characterized by means of elemental analysis, IR spectra and TGA analysis. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

Original language	English
Pages (from-to)	705-710
Number of pages	6
Journal	Solid State Sciences
Volume	2
Issue number	7
DOIs	https://doi.org/10.1016/S1293-2558(00)01076-1
Publication status	Published - 2000
Externally published	Yes

Keywords

Crystal structures
Hydrothermal synthesis
Metal-oxo clusters
Nickel complexes

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10.1016/S1293-2558(00)01076-1

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@article{62771275581c4eccb83839e972eb64ca,

title = "Hydrothermal synthesis and characterization of [Ni(phen)3]2[Mo8O26]·2H2O",

abstract = "The reaction of MoO3, H2MoO4 and Ni(Ac)2·6H2O with 1,10-phenanthroline by a hydrothermal method furnishes the discrete cluster [Ni(phen)3]2[Mo8O26]·2H2O (1). The structure of 1 is triclinic, space group (P{\=l}), a = 11.4965(10), b = 11.6829(13), c = 15.1518(15) {\AA} α = 83.032(8), β = 71.557(7), γ = 78.319(7)°, R = 0.0433 for 7397 observed [I > 2<σ(I)] reflections. The crystallographically determined solid state structure of 1 shows that the cluster consists of two complex cations, one cluster anion [Mo8O26]4- and two water molecules of crystallization. Each nickel ion is coordinated by six nitrogen atoms from three phenanthroline ligands, forming a distorted octahedron, and the anion has a β-configuration formed by eight edge-sharing MoO6 octahedra. Compound 1 was characterized by means of elemental analysis, IR spectra and TGA analysis. (C) 2000 Editions scientifiques et medicales Elsevier SAS.",

keywords = "Crystal structures, Hydrothermal synthesis, Metal-oxo clusters, Nickel complexes",

author = "Wang, {R. Z.} and Xu, {J. Q.} and Yang, {G. Y.} and Li, {Y. F.} and Xing, {Y. H.} and Li, {D. M.} and Liu, {S. Q.} and Bu, {W. M.} and L. Ye and Fan, {Y. G.}",

year = "2000",

doi = "10.1016/S1293-2558(00)01076-1",

language = "English",

volume = "2",

pages = "705--710",

journal = "Solid State Sciences",

issn = "1293-2558",

publisher = "Elsevier Masson s.r.l.",

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TY - JOUR

T1 - Hydrothermal synthesis and characterization of [Ni(phen)3]2[Mo8O26]·2H2O

AU - Wang, R. Z.

AU - Xu, J. Q.

AU - Yang, G. Y.

AU - Li, Y. F.

AU - Xing, Y. H.

AU - Li, D. M.

AU - Liu, S. Q.

AU - Bu, W. M.

AU - Ye, L.

AU - Fan, Y. G.

PY - 2000

Y1 - 2000

N2 - The reaction of MoO3, H2MoO4 and Ni(Ac)2·6H2O with 1,10-phenanthroline by a hydrothermal method furnishes the discrete cluster [Ni(phen)3]2[Mo8O26]·2H2O (1). The structure of 1 is triclinic, space group (Pl̄), a = 11.4965(10), b = 11.6829(13), c = 15.1518(15) Å α = 83.032(8), β = 71.557(7), γ = 78.319(7)°, R = 0.0433 for 7397 observed [I > 2<σ(I)] reflections. The crystallographically determined solid state structure of 1 shows that the cluster consists of two complex cations, one cluster anion [Mo8O26]4- and two water molecules of crystallization. Each nickel ion is coordinated by six nitrogen atoms from three phenanthroline ligands, forming a distorted octahedron, and the anion has a β-configuration formed by eight edge-sharing MoO6 octahedra. Compound 1 was characterized by means of elemental analysis, IR spectra and TGA analysis. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

AB - The reaction of MoO3, H2MoO4 and Ni(Ac)2·6H2O with 1,10-phenanthroline by a hydrothermal method furnishes the discrete cluster [Ni(phen)3]2[Mo8O26]·2H2O (1). The structure of 1 is triclinic, space group (Pl̄), a = 11.4965(10), b = 11.6829(13), c = 15.1518(15) Å α = 83.032(8), β = 71.557(7), γ = 78.319(7)°, R = 0.0433 for 7397 observed [I > 2<σ(I)] reflections. The crystallographically determined solid state structure of 1 shows that the cluster consists of two complex cations, one cluster anion [Mo8O26]4- and two water molecules of crystallization. Each nickel ion is coordinated by six nitrogen atoms from three phenanthroline ligands, forming a distorted octahedron, and the anion has a β-configuration formed by eight edge-sharing MoO6 octahedra. Compound 1 was characterized by means of elemental analysis, IR spectra and TGA analysis. (C) 2000 Editions scientifiques et medicales Elsevier SAS.

KW - Crystal structures

KW - Hydrothermal synthesis

KW - Metal-oxo clusters

KW - Nickel complexes

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U2 - 10.1016/S1293-2558(00)01076-1

DO - 10.1016/S1293-2558(00)01076-1

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JO - Solid State Sciences

JF - Solid State Sciences

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ER -

Hydrothermal synthesis and characterization of [Ni(phen)₃]₂[Mo₈O₂₆]·2H₂O

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